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@ARTICLE{Lewerenz:866900,
author = {Lewerenz, Meinert and Käbitz, Stefan and Knips, Marcus and
Münnix, Jens and Schmalstieg, Johannes and Warnecke,
Alexander and Sauer, Dirk Uwe},
title = {{N}ew method evaluating currents keeping the voltage
constant for fast and highly resolved measurement of
{A}rrhenius relation and capacity fade},
journal = {Journal of power sources},
volume = {353},
issn = {0378-7753},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2019-05960},
pages = {144 - 151},
year = {2017},
abstract = {The evaluation of floating currents is a powerful method to
characterize capacity fade induced by calendaric aging and
enables a highly resolved representation of the Arrhenius
relation. The test arrangement is simple and could
constitute a cheap alternative to state-of-the-art
calendaric aging tests including check-up tests. Therefore
the currents to maintain a constant voltage are evaluated.
This method is validated by analyzing nine cylindrical 8 Ah
LiFePO4|Graphite battery cells during calendaric aging at 25
°C, 40 °C and 60 °C at 3.6 V $(100\%$ SOC). The 3.6 V are
kept by applying constant voltage while the floating
currents are logged. The floating currents correlate with
the rate of capacity loss measured during capacity tests.
The floating currents reveal to be rather constant at 25
°C, linearly increasing at 40 °C and decreasing from a
higher level at 60 °C. Additional tests with three test
cells, with the temperature rising from 40 to 60 °C in
steps of 5 K, exhibit non-constant currents starting from 50
°C on with high variations amongst the tested cells. Once
stored above 50 °C, the cells exhibit increased floating
currents compared to the measurement at the same temperature
before exceeding 50 °C.},
cin = {IEK-12},
ddc = {620},
cid = {I:(DE-Juel1)IEK-12-20141217},
pnm = {131 - Electrochemical Storage (POF3-131)},
pid = {G:(DE-HGF)POF3-131},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000401208100017},
doi = {10.1016/j.jpowsour.2017.03.136},
url = {https://juser.fz-juelich.de/record/866900},
}