TY - JOUR
AU - Krieger, Viktoria
AU - Hamacher, Alexandra
AU - Cao, Fangyuan
AU - Stenzel, Katharina
AU - Gertzen, Christoph G. W.
AU - Schäker-Hübner, Linda
AU - Kurz, Thomas
AU - Gohlke, Holger
AU - Dekker, Frank J.
AU - Kassack, Matthias U.
AU - Hansen, Finn K.
TI - Synthesis of peptoid-based class I selective histone deacetylase inhibitors with chemosensitizing properties
JO - Journal of medicinal chemistry
VL - 62
IS - 24
SN - 1520-4804
CY - Washington, DC
PB - ACS
M1 - FZJ-2019-06042
SP - 11260-11279
PY - 2019
AB - There is increasing evidence that histone deacetylase (HDAC) inhibitors can (re)sensitize cancer cells for chemotherapeutics via ‘epigenetic priming’. In this work, we describe the synthesis of a series of class I selective HDAC inhibitors with 2-aminoanilides as zinc-binding groups. Several of the synthesized compounds revealed potent inhibition of the class I HDAC isoforms HDAC1, 2 and/or 3 and promising antiproliferative effects in the human ovarian cancer cell line A2780 and the human squamous carcinoma cell line Cal27. Selected compounds were investigated in a cellular model of platinum resistance. In particular compound 2a revealed potent chemosensitizing properties and full reversal of cisplatin resistance in Cal27CisR cells. This effect is related to a synergistic increase in caspase 3/7 activation and induction of apoptosis. Thus, this work demonstrates that pan-HDAC inhibition or dual class I/class IIb inhibition is not required for full reversal of cisplatin resistance.
LB - PUB:(DE-HGF)16
C6 - pmid:31762274
UR - <Go to ISI:>//WOS:000505633400020
DO - DOI:10.1021/acs.jmedchem.9b01489
UR - https://juser.fz-juelich.de/record/867366
ER -