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| Hauptseite > Publikationsdatenbank > Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety > print |
| Hauptseite > Publikationsdatenbank > Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety > print |
| 001 | 867470 | ||
| 005 | 20210130003739.0 | ||
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| 100 | 1 | _ | |a Klauke, Karsten |0 P:(DE-HGF)0 |b 0 |e Corresponding author |
| 245 | _ | _ | |a Silver, Gold, Palladium, and Platinum N-heterocyclic Carbene Complexes Containing a Selenoether-Functionalized Imidazol-2-ylidene Moiety |
| 260 | _ | _ | |a Washington, DC |c 2018 |b ACS Publ. |
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| 520 | _ | _ | |a The selenoether-functionalized imidazolium salt N-[(phenylseleno)methylene)]-N′-methylimidazolium chloride (LH+Cl–) was transformed into the metal–carbene complexes [AgCl(L)], [AuCl(L)], [PdCl2(L)], and [PtCl2(L)] by the reaction with Ag2O and an additional transmetalation reaction of [AgCl(L)] with [(THT)AuCl], [(COD)PdCl2], and [(COD)PtCl2], respectively (THT = tetrahydrothiophene, COD = cyclooctadiene). The compound [AuI2Cl(L)] was prepared by oxidation of [AuCl(L)] with elemental iodine. The microwave-assisted decomposition of [PdCl2(L)] in the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([BMIm]NTf2) or in propylene carbonate led to the formation of Pd17Se15 nanoparticles of 51 ± 17 or 26 ± 7 nm diameter, respectively. The decomposition of the platinum complex resulted in either small Pt clusters around 1 nm size from the ionic liquid suspension or Pt nanoparticles of 3 ± 1 nm diameter in propylene carbonate. High-resolution X-ray photoelectron spectroscopy (HR-XPS) and 13C cross-polarization magic-angle spinning (CP MAS) NMR indicated that the surface of Pt clusters and crystalline Pt nanoparticles is formed by an amorphous Pt(II)/Se shell and by carbene ligand residues. |
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| 773 | _ | _ | |a 10.1021/acs.organomet.7b00678 |g Vol. 37, no. 3, p. 298 - 308 |0 PERI:(DE-600)2006302-7 |n 3 |p 298 - 308 |t Organometallics |v 37 |y 2018 |x 1520-6041 |
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