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000867471 1001_ $$00000-0002-7754-4386$$aKlauke, Karsten$$b0
000867471 245__ $$aThermodynamic properties of selenoether-functionalized ionic liquids and their use for the synthesis of zinc selenide nanoparticles
000867471 260__ $$aLondon$$bSoc.$$c2018
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000867471 520__ $$aThree selenoether-functionalized ionic liquids (ILs) of N-[(phenylseleno)methylene]pyridinium (1), N-(methyl)- (2) and N-(butyl)-N‘-[(phenylseleno)methylene]imidazolium (3) with bis(trifluoromethanesulfonyl)imide anions ([NTf2]) were prepared from pyridine, N-methylimidazole and N-butylimidazole with in situ obtained phenylselenomethyl chloride, followed by ion exchange to give the desired compounds. The crystal structures of the bromide and tetraphenylborate salts of the above cations (1-Br, 2-BPh4 and 3-BPh4) confirm the formation of the desired cations and indicate a multitude of different supramolecular interactions besides the dominating Coulomb interactions between the cations and anions. The vaporization enthalpies of the synthesized [NTf2]-containing ILs were determined by means of a quartz-crystal microbalance method (QCM) and their densities were measured with an oscillating U-tube. These thermodynamic data have been used to develop a method for assessment of miscibility of conventional solvents in the selenium-containing ILs by using Hildebrandt solubility parameters, as well as for modeling with the electrolyte perturbed-chain statistical associating fluid theory (ePC-SAFT) method. Furthermore, structure–property relations between selenoether-functionalized and similarly shaped corresponding aryl-substituted imidazolium- and pyridinium-based ILs were analyzed and showed that the contribution of the selenium moiety to the enthalpy of vaporization of an IL is equal to the contribution of a methylene (CH2) group. An incremental approach to predict vaporization enthalpies of ILs by a group contribution method has been developed. The reaction of these ILs with zinc acetate dihydrate under microwave irradiation led to ZnSe nanoparticles of an average diameter between 4 and 10 nm, depending on the reaction conditions
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000867471 7001_ $$00000-0002-4002-7019$$aZaitsau, Dzmitry H.$$b1
000867471 7001_ $$0P:(DE-HGF)0$$aBülow, Mark$$b2
000867471 7001_ $$0P:(DE-HGF)0$$aHe, Li$$b3
000867471 7001_ $$00000-0003-2318-8731$$aKlopotowski, Maximilian$$b4
000867471 7001_ $$0P:(DE-HGF)0$$aKnedel, Tim-Oliver$$b5
000867471 7001_ $$0P:(DE-Juel1)130525$$aBarthel, Juri$$b6
000867471 7001_ $$00000-0003-1074-177X$$aHeld, Christoph$$b7$$eCorresponding author
000867471 7001_ $$00000-0002-0957-5594$$aVerevkin, Sergey P.$$b8$$eCorresponding author
000867471 7001_ $$00000-0002-6288-9605$$aJaniak, Christoph$$b9$$eCorresponding author
000867471 773__ $$0PERI:(DE-600)1472887-4$$a10.1039/C8DT00233A$$gVol. 47, no. 14, p. 5083 - 5097$$n14$$p5083 - 5097$$tDalton transactions$$v47$$x0300-9246$$y2018
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