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@ARTICLE{Klauke:867471,
      author       = {Klauke, Karsten and Zaitsau, Dzmitry H. and Bülow, Mark
                      and He, Li and Klopotowski, Maximilian and Knedel,
                      Tim-Oliver and Barthel, Juri and Held, Christoph and
                      Verevkin, Sergey P. and Janiak, Christoph},
      title        = {{T}hermodynamic properties of selenoether-functionalized
                      ionic liquids and their use for the synthesis of zinc
                      selenide nanoparticles},
      journal      = {Dalton transactions},
      volume       = {47},
      number       = {14},
      issn         = {0300-9246},
      address      = {London},
      publisher    = {Soc.},
      reportid     = {FZJ-2019-06110},
      pages        = {5083 - 5097},
      year         = {2018},
      abstract     = {Three selenoether-functionalized ionic liquids (ILs) of
                      N-[(phenylseleno)methylene]pyridinium (1), N-(methyl)- (2)
                      and N-(butyl)-N‘-[(phenylseleno)methylene]imidazolium (3)
                      with bis(trifluoromethanesulfonyl)imide anions ([NTf2]) were
                      prepared from pyridine, N-methylimidazole and
                      N-butylimidazole with in situ obtained phenylselenomethyl
                      chloride, followed by ion exchange to give the desired
                      compounds. The crystal structures of the bromide and
                      tetraphenylborate salts of the above cations (1-Br, 2-BPh4
                      and 3-BPh4) confirm the formation of the desired cations and
                      indicate a multitude of different supramolecular
                      interactions besides the dominating Coulomb interactions
                      between the cations and anions. The vaporization enthalpies
                      of the synthesized [NTf2]-containing ILs were determined by
                      means of a quartz-crystal microbalance method (QCM) and
                      their densities were measured with an oscillating U-tube.
                      These thermodynamic data have been used to develop a method
                      for assessment of miscibility of conventional solvents in
                      the selenium-containing ILs by using Hildebrandt solubility
                      parameters, as well as for modeling with the electrolyte
                      perturbed-chain statistical associating fluid theory
                      (ePC-SAFT) method. Furthermore, structure–property
                      relations between selenoether-functionalized and similarly
                      shaped corresponding aryl-substituted imidazolium- and
                      pyridinium-based ILs were analyzed and showed that the
                      contribution of the selenium moiety to the enthalpy of
                      vaporization of an IL is equal to the contribution of a
                      methylene (CH2) group. An incremental approach to predict
                      vaporization enthalpies of ILs by a group contribution
                      method has been developed. The reaction of these ILs with
                      zinc acetate dihydrate under microwave irradiation led to
                      ZnSe nanoparticles of an average diameter between 4 and 10
                      nm, depending on the reaction conditions},
      cin          = {ER-C-2},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-2-20170209},
      pnm          = {131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:29561056},
      UT           = {WOS:000429743700037},
      doi          = {10.1039/C8DT00233A},
      url          = {https://juser.fz-juelich.de/record/867471},
}