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@INPROCEEDINGS{Park:867761,
author = {Park, Gunwoo and Brito, Mariano and Naegele, Gerhard},
title = {{T}he effect of dispersion transport properties on the
concentration-polarization layer in crossflow
ultrafiltration},
reportid = {FZJ-2019-06376},
year = {2019},
abstract = {Crossflow filtration is a pressure-driven separation and
enrichment process for colloidal dispersions where the feed
dispersion is continuously pumped through a membrane pipe.
The transmembrane pressure (TMP) causes solvent to flow out
of the membrane, while the colloidal particles are retained
inside the pipe. Consequently, a particles-enriched diffuse
layer is formed near the membrane wall which reduces the
filtration efficiency. This so-called
concentration-polarization (CP) layer is due to the balance
of flow advection of particles towards and gradient
diffusion away from the membrane. In the ultrafiltration
regime where Brownian motion dominates flow convection, the
collective diffusion coefficient and the dispersion
viscosity are the key transport properties determining the
CP layer in conjunction with the TMP and transmembrane
osmotic pressure. In this study, we present a finite-element
(FEM) method for calculating the CP layer and suspension
flow profiles in a crossflow ultrafiltration setup [1]. We
show that the FEM-calculated CP layer profiles are in
quantitative agreement with results obtained from a
simplifying boundary layer analysis [1]. Results for the
filtration and flow profiles are discussed for different
globular dispersion particles including colloidal hard
spheres (as a reference system), solvent-permeable particles
such as non-ionic microgels [2], impermeable
charge-stabilized particles [3], and ionic microgels with
concentration-dependent size [4]. We pay particular
attention to the effect of the different transport
properties and osmotic pressure dependencies on the
ultrafiltration profiles.References[1] G. W. Park and G.
Nägele, “Analytic and numerical approaches to
concentration-polarization layers in cross-flow
ultrafiltration with a cylindrical membrane pipe” (in
preparation)[2] R. Roa et al., “Ultrafiltration modeling
of non-ionic microgels,” Soft Matter 11, 4106-4122 (2015)
[3] R. Roa et al., “Ultrafiltration of charge-stabilized
dispersions at low salinity,” Soft Matter 12,4638-4653
(2016)[4] M. Brito et al., “Deswelling effects on
structural and transport properties of ionic
microgelsuspensions” (in preparation)},
month = {Jun},
date = {2019-06-03},
organization = {International Soft Matter Conference,
Edinburgh (UK), 3 Jun 2019 - 7 Jun
2019},
subtyp = {After Call},
cin = {ICS-3},
cid = {I:(DE-Juel1)ICS-3-20110106},
pnm = {551 - Functional Macromolecules and Complexes (POF3-551) /
SFB 985 B06 - Kontinuierliche Trennung und Aufkonzentrierung
von Mikrogelen (B06) (221475706)},
pid = {G:(DE-HGF)POF3-551 / G:(GEPRIS)221475706},
typ = {PUB:(DE-HGF)24},
url = {https://juser.fz-juelich.de/record/867761},
}