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@ARTICLE{Hofmann:867787,
      author       = {Hofmann, Eddie and Dulle, Martin and Liao, Xiaojian and
                      Greiner, Andreas and Förster, Stephan},
      title        = {{C}ontrolling {P}olymer {M}icrofiber {S}tructure by {M}icro
                      {S}olution {B}low {S}pinning},
      journal      = {Macromolecular chemistry and physics},
      volume       = {221},
      number       = {1},
      issn         = {1521-3935},
      address      = {Weinheim},
      publisher    = {Wiley-VCH},
      reportid     = {FZJ-2019-06397},
      pages        = {1900453 -},
      year         = {2019},
      abstract     = {Recent progress in microfluidic technology allows
                      fabricating microfluidic devices to produce liquid microjets
                      with unprecedented control of the jet diameter and velocity.
                      Here it is demonstrated that microfluidic devices based on
                      the gas dynamic virtual nozzle principle can be excellently
                      used for micro solution blow spinning to continuously
                      fabricate microfibers with excellent control of the fiber
                      diameter and the internal crystalline alignment that
                      determines the mechanical properties. Fiber spinning
                      experiments with small‐ and wide‐angle X‐ray
                      scattering are combined to directly relate the macroscopic
                      spinning conditions to the bulk and molecular structure of
                      the resulting fibers. The elongational rate is shown as the
                      relevant parameter that transduces the nozzle flow
                      conditions to the local macromolecular structure and
                      orientation, and thus the mechanical properties of the
                      resulting fiber. It is observed that the spinning process
                      results in very uniform microfibers with a well‐defined
                      shish–kebab crystal structure, which evolves into an
                      extended chain crystal structure upon plastic deformation.
                      Thus, the presented microfluidic spinning methodology has
                      great implications for a precisely controlled production of
                      microfibers using miniaturized spinning devices.},
      cin          = {JCNS-1 / ICS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)ICS-1-20110106},
      pnm          = {551 - Functional Macromolecules and Complexes (POF3-551) /
                      6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
                      / 6215 - Soft Matter, Health and Life Sciences (POF3-621)},
      pid          = {G:(DE-HGF)POF3-551 / G:(DE-HGF)POF3-6G4 /
                      G:(DE-HGF)POF3-6215},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000501355800001},
      doi          = {10.1002/macp.201900453},
      url          = {https://juser.fz-juelich.de/record/867787},
}