TY - JOUR AU - Wang, Ruining AU - Lange, Felix R. L. AU - Cecchi, Stefano AU - Hanke, Michael AU - Wuttig, Matthias AU - Calarco, Raffaella TI - 2D or Not 2D: Strain Tuning in Weakly Coupled Heterostructures JO - Advanced functional materials VL - 28 IS - 14 SN - 1616-301X CY - Weinheim PB - Wiley-VCH M1 - FZJ-2019-06544 SP - 1705901 - PY - 2018 AB - A route to realize strain engineering in weakly bonded heterostructures is presented. Such heterostructures, consisting of layered materials with a pronounced bond hierarchy of strong and weak bonds within and across their building blocks respectively, are anticipated to grow decoupled from each other. Hence, they are expected to be unsuitable for strain engineering as utilized for conventional materials which are strongly bonded isotropically. Here, it is shown for the first time that superlattices of layered chalcogenides (Sb2Te3/GeTe) behave neither as fully decoupled two‐dimensional (2D) materials nor as covalently bonded three‐dimensional (3D) materials. Instead, they form a novel class of 3D solids with an unparalleled atomic arrangement, featuring a distribution of lattice constants, which is tunable. A map to identify further material combinations with similar characteristic is given. It opens the way for the design of a novel class of artificial solids with unexplored properties LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000429410400006 DO - DOI:10.1002/adfm.201705901 UR - https://juser.fz-juelich.de/record/867951 ER -