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@ARTICLE{Raty:867959,
author = {Raty, Jean‐Yves and Schumacher, Mathias and Golub, Pavlo
and Deringer, Volker L. and Gatti, Carlo and Wuttig,
Matthias},
title = {{A} {Q}uantum‐{M}echanical {M}ap for {B}onding and
{P}roperties in {S}olids},
journal = {Advanced materials},
volume = {31},
number = {3},
issn = {1521-4095},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2019-06552},
pages = {1806280 -},
year = {2019},
abstract = {A 2D map is created for solid‐state materials based on a
quantum‐mechanical description of electron sharing and
electron transfer. This map intuitively identifies the
fundamental nature of ionic, metallic, and covalent bonding
in a range of elements and binary compounds; furthermore, it
highlights a distinct region for a mechanism recently termed
“metavalent” bonding. Then, it is shown how this
materials map can be extended in the third dimension by
including physical properties of application interest.
Finally, it is shown how the map coordinates yield new
insight into the nature of the Peierls distortion in
phase‐change materials and thermoelectrics. These findings
and conceptual approaches provide a novel avenue to tailor
material properties.},
cin = {PGI-10},
ddc = {660},
cid = {I:(DE-Juel1)PGI-10-20170113},
pnm = {521 - Controlling Electron Charge-Based Phenomena
(POF3-521)},
pid = {G:(DE-HGF)POF3-521},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:30474156},
UT = {WOS:000459628200023},
doi = {10.1002/adma.201806280},
url = {https://juser.fz-juelich.de/record/867959},
}