% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{SchulzeKppers:867999,
author = {Schulze-Küppers, F. and Baumann, S. and Meulenberg, W. A.
and Bouwmeester, H. J. M.},
title = {{I}nfluence of support layer resistance on oxygen fluxes
through asymmetric membranes based on perovskite-type oxides
{S}r{T}i1-{F}e {O}3-δ},
journal = {Journal of membrane science},
volume = {596},
issn = {0376-7388},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2019-06592},
pages = {117704 -},
year = {2020},
abstract = {Asymmetric membranes of mixed ionic-electronic conducting
perovskite-type oxides SrTi1-xFexO3-δ (STF, x = 0.3, 0.5
and 0.7) were prepared by inverse sequential tape-casting.
Both porous support (~600 μm) and functional membrane layer
(~20 μm) for a given membrane assembly were made from the
same composition to ensure thermochemical compatibility
between the layers. Oxygen fluxes were assessed in the range
650 -1020 °C, using either (non-pressurized) ambient air or
pure oxygen as feed gas at the support side of the
asymmetric membrane and argon as sweep gas. Notably, similar
oxygen fluxes (~1.2 × 10−6 mol cm−2 s−1) are measured
through the membranes of different compositions above 950
°C when using ambient air as feed gas. This observation is
interpreted to reflect the major role of the support layer
resistance in rate-limiting the oxygen fluxes through the
STF asymmetric membranes, which conclusion is supported by
comparison of the oxygen fluxes with those measured
previously through asymmetric membranes of
Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) and
La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF). A simple
diffusion-convection model is used to account for the
observed gas phase polarization in the porous support layers
limiting the oxygen fluxes.},
cin = {IEK-1},
ddc = {570},
cid = {I:(DE-Juel1)IEK-1-20101013},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000512677400026},
doi = {10.1016/j.memsci.2019.117704},
url = {https://juser.fz-juelich.de/record/867999},
}