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000868096 1001_ $$00000-0003-2996-3604$$aBianchi, Federico$$b0$$eCorresponding author
000868096 245__ $$aHighly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol
000868096 260__ $$aWashington, DC$$bACS Publ.$$c2019
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000868096 520__ $$aHighly oxygenated organic molecules (HOM) are formed in the atmosphere via autoxidation involving peroxy radicals arising from volatile organic compounds (VOC). HOM condense on pre-existing particles and can be involved in new particle formation. HOM thus contribute to the formation of secondary organic aerosol (SOA), a significant and ubiquitous component of atmospheric aerosol known to affect the Earth’s radiation balance. HOM were discovered only very recently, but the interest in these compounds has grown rapidly. In this Review, we define HOM and describe the currently available techniques for their identification/quantification, followed by a summary of the current knowledge on their formation mechanisms and physicochemical properties. A main aim is to provide a common frame for the currently quite fragmented literature on HOM studies. Finally, we highlight the existing gaps in our understanding and suggest directions for future HOM research.
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000868096 7001_ $$00000-0002-6416-4931$$aKurtén, Theo$$b1
000868096 7001_ $$0P:(DE-HGF)0$$aRiva, Matthieu$$b2
000868096 7001_ $$0P:(DE-HGF)0$$aMohr, Claudia$$b3
000868096 7001_ $$00000-0003-0463-8098$$aRissanen, Matti P.$$b4
000868096 7001_ $$0P:(DE-HGF)0$$aRoldin, Pontus$$b5
000868096 7001_ $$00000-0003-2014-6018$$aBerndt, Torsten$$b6
000868096 7001_ $$00000-0001-5443-729X$$aCrounse, John D.$$b7
000868096 7001_ $$00000-0002-6126-3854$$aWennberg, Paul O.$$b8
000868096 7001_ $$0P:(DE-Juel1)16346$$aMentel, Thomas F.$$b9
000868096 7001_ $$0P:(DE-Juel1)129421$$aWildt, Jürgen$$b10
000868096 7001_ $$0P:(DE-HGF)0$$aJunninen, Heikki$$b11
000868096 7001_ $$0P:(DE-HGF)0$$aJokinen, Tuija$$b12
000868096 7001_ $$0P:(DE-HGF)0$$aKulmala, Markku$$b13
000868096 7001_ $$0P:(DE-HGF)0$$aWorsnop, Douglas R.$$b14
000868096 7001_ $$00000-0002-5098-4867$$aThornton, Joel A.$$b15
000868096 7001_ $$00000-0003-3054-2364$$aDonahue, Neil$$b16
000868096 7001_ $$00000-0002-7275-8297$$aKjaergaard, Henrik G.$$b17
000868096 7001_ $$0P:(DE-Juel1)144056$$aEhn, Mikael$$b18
000868096 773__ $$0PERI:(DE-600)2003609-7$$a10.1021/acs.chemrev.8b00395$$gVol. 119, no. 6, p. 3472 - 3509$$n6$$p3472 - 3509$$tChemical reviews$$v119$$x1520-6890$$y2019
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