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@ARTICLE{Lang:868385,
      author       = {Lang, Christian and Kohlbrecher, Joachim and Porcar, Lionel
                      and Radulescu, Aurel and Sellinghoff, Karin and Dhont, Jan
                      Karel George and Lettinga, Minne Paul},
      title        = {{M}icrostructural {U}nderstanding of the {L}ength- and
                      {S}tiffness-{D}ependent {S}hear {T}hinning in {S}emidilute
                      {C}olloidal {R}ods},
      journal      = {Macromolecules},
      volume       = {52},
      number       = {24},
      issn         = {1520-5835},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2020-00001},
      pages        = {9604 - 9612},
      year         = {2019},
      abstract     = {Complex fluids containing low concentrations of slender
                      colloidal rods can display a high viscosity, while little
                      flow is needed to thin the fluid. This feature makes slender
                      rods essential constituents in industrial applications and
                      biology. Though this behavior strongly depends on the
                      rod-length, so far no direct relation could be identified.
                      We employ a library of filamentous viruses to study the
                      effect of rod size and flexibility on the zero-shear
                      viscosity and shear-thinning behavior. Rheology and
                      small-angle neutron scattering data are compared to a
                      revised version of the standard theory for ideally stiff
                      rods, which incorporates a complete shear-induced dilation
                      of the confinement. While the earlier predicted
                      length-independent prefactor of the restricted rotational
                      diffusion coefficient is confirmed by varying the length and
                      concentration of the rods, the revised theory correctly
                      predicts the shear-thinning behavior as well as the
                      underlying orientational order. These results can be
                      directly applied to understand the manifold systems based on
                      rodlike colloids and design new materials.},
      cin          = {JCNS-FRM-II / JCNS-1 / MLZ / ICS-3},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)ICS-3-20110106},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
                      G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS2-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000505629900020},
      doi          = {10.1021/acs.macromol.9b01592},
      url          = {https://juser.fz-juelich.de/record/868385},
}