TY - JOUR AU - Mathias, S. AU - Ruffing, A. AU - Deicke, F. AU - Wiesenmayer, M. AU - Sakar, I. AU - Bihlmayer, G. AU - Chulkov, E. V. AU - Koroteev, Yu. M. AU - Echenique, P. M. AU - Bauer, M. AU - Aeschlimann, M. TI - Quantum-well induced giant spin-orbit splitting JO - Physical review letters VL - 104 SN - 0031-9007 CY - College Park, Md. PB - APS M1 - PreJuSER-8721 SP - 066802 PY - 2010 N1 - This work was supported by the DFG GRK 792 and the DFG SFB/TRR49, the UPV/EHU (Grant No. GIC07IT36607), the Departamento de Educacion del Gobierno Vasco, and the Spanish MCyT (Grant No. FIS200766711C0101). AB - We report on the observation of a giant spin-orbit splitting of quantum-well states in the unoccupied electronic structure of a Bi monolayer on Cu(111). Up to now, Rashba-type splittings of this size have been reported exclusively for surface states in a partial band gap. With these quantum-well states we have experimentally identified a second class of states that show a huge spin-orbit splitting. First-principles electronic structure calculations show that the origin of the spin-orbit splitting is due to the perpendicular potential at the surface and interface of the ultrathin Bi film. This finding allows for the direct possibility to tailor spin-orbit splitting by means of thin-film nanofabrication. KW - J (WoSType) LB - PUB:(DE-HGF)16 UR - <Go to ISI:>//WOS:000274445100039 DO - DOI:10.1103/PhysRevLett.104.066802 UR - https://juser.fz-juelich.de/record/8721 ER -