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000872843 1001_ $$0P:(DE-Juel1)168420$$aWu, Xiaochao$$b0$$eCorresponding author$$ufzj
000872843 245__ $$aMorphology-controllable synthesis of LiCoPO4 and its influence on electrochemical performance for high-voltage lithium ion batteries
000872843 260__ $$aNew York, NY [u.a.]$$bElsevier$$c2020
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000872843 520__ $$aLiCoPO4 is a cathode material for 5V lithium ion batteries, but in practice it often suffers from the poor electrochemical performance due to its intrinsically slow ionic diffusion. Herein, various LiCoPO4 materials with different morphology, including unstructured nanoparticle, nanorod and microrod shape, have been synthesized by solvothermal methods and a subsequent annealing process in air. Electrochemical analysis shows that the controllable morphology has an influence in electronic and ionic pathways, thus affects the electrochemical performance. The nanorod shape LiCoPO4 shows the largest discharge capacity, the best rate capability and best cycling stability. Furthermore, the apparent Li+ ion diffusion coefficients of LiCoPO4 samples were determined to investigate the influence of particle shape and the orientation on the Li+ ions migration.
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000872843 536__ $$0G:(DE-Juel1)HITEC-20170406$$aHITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406)$$cHITEC-20170406$$x1
000872843 7001_ $$0P:(DE-Juel1)174171$$aMeledina, Maria$$b1$$ufzj
000872843 7001_ $$0P:(DE-Juel1)161208$$aTempel, Hermann$$b2$$ufzj
000872843 7001_ $$0P:(DE-Juel1)157700$$aKungl, Hans$$b3$$ufzj
000872843 7001_ $$0P:(DE-Juel1)130824$$aMayer, Joachim$$b4$$ufzj
000872843 7001_ $$0P:(DE-Juel1)156123$$aEichel, Rüdiger-A.$$b5$$ufzj
000872843 773__ $$0PERI:(DE-600)1491915-1$$a10.1016/j.jpowsour.2020.227726$$p227726$$tJournal of power sources$$v450$$x0378-7753$$y2020
000872843 8564_ $$uhttps://juser.fz-juelich.de/record/872843/files/Wu_etal.pdf$$yPublished on 2020-01-29. Available in OpenAccess from 2022-01-29.
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