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@ARTICLE{Wu:872843,
      author       = {Wu, Xiaochao and Meledina, Maria and Tempel, Hermann and
                      Kungl, Hans and Mayer, Joachim and Eichel, Rüdiger-A.},
      title        = {{M}orphology-controllable synthesis of {L}i{C}o{PO}4 and
                      its influence on electrochemical performance for
                      high-voltage lithium ion batteries},
      journal      = {Journal of power sources},
      volume       = {450},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2020-00313},
      pages        = {227726},
      year         = {2020},
      abstract     = {LiCoPO4 is a cathode material for 5V lithium ion batteries,
                      but in practice it often suffers from the poor
                      electrochemical performance due to its intrinsically slow
                      ionic diffusion. Herein, various LiCoPO4 materials with
                      different morphology, including unstructured nanoparticle,
                      nanorod and microrod shape, have been synthesized by
                      solvothermal methods and a subsequent annealing process in
                      air. Electrochemical analysis shows that the controllable
                      morphology has an influence in electronic and ionic
                      pathways, thus affects the electrochemical performance. The
                      nanorod shape LiCoPO4 shows the largest discharge capacity,
                      the best rate capability and best cycling stability.
                      Furthermore, the apparent Li+ ion diffusion coefficients of
                      LiCoPO4 samples were determined to investigate the influence
                      of particle shape and the orientation on the Li+ ions
                      migration.},
      cin          = {IEK-9 / ER-C-2},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-9-20110218 / I:(DE-Juel1)ER-C-2-20170209},
      pnm          = {131 - Electrochemical Storage (POF3-131) / HITEC -
                      Helmholtz Interdisciplinary Doctoral Training in Energy and
                      Climate Research (HITEC) (HITEC-20170406)},
      pid          = {G:(DE-HGF)POF3-131 / G:(DE-Juel1)HITEC-20170406},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000517663800044},
      doi          = {10.1016/j.jpowsour.2020.227726},
      url          = {https://juser.fz-juelich.de/record/872843},
}