000872925 001__ 872925
000872925 005__ 20240712113155.0
000872925 0247_ $$2doi$$a10.1021/acs.chemmater.9b04811
000872925 0247_ $$2ISSN$$a0897-4756
000872925 0247_ $$2ISSN$$a1520-5002
000872925 0247_ $$2Handle$$a2128/26214
000872925 0247_ $$2altmetric$$aaltmetric:88450991
000872925 0247_ $$2WOS$$aWOS:000513299400032
000872925 037__ $$aFZJ-2020-00390
000872925 082__ $$a540
000872925 1001_ $$0P:(DE-HGF)0$$aLi, Weihan$$b0
000872925 245__ $$aPhosphorene Degradation: Visualization and Quantification of Nanoscale Phase Evolution by Scanning Transmission X-ray Microscopy
000872925 260__ $$aWashington, DC$$bAmerican Chemical Society$$c2020
000872925 3367_ $$2DRIVER$$aarticle
000872925 3367_ $$2DataCite$$aOutput Types/Journal article
000872925 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1605711724_23295
000872925 3367_ $$2BibTeX$$aARTICLE
000872925 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000872925 3367_ $$00$$2EndNote$$aJournal Article
000872925 520__ $$aPhosphorene, single- or few-layered black phosphorus, has been rediscovered as a promising two-dimensional material owing to its unique optical, thermal, and electrical properties with potential applications in optoelectronics, nanoelectronics, and energy storage. However, rapid degradation under ambient condition highly limits the practical applications of phosphorene. Solving the degradation problem demands an understanding of the oxidization process. We, for the first time, apply synchrotron-based X-ray photoelectron spectroscopy (XPS), X-ray absorption near-edge structure (XANES), and scanning transmission X-ray microscopy (STXM) for the nanoscale chemical imaging of phosphorene degradation. Through these methods, we have identified chemical details of the morphological effect and clarified thickness and proximity effects, which control the oxidization process. Furthermore, the entire oxidization process of phosphorene has also been studied by in situ XPS and XANES, showing the step-by-step oxidization process under the ambient condition. Theoretical calculations at the density functional theory level support experimental findings. This detailed study provides a better understanding of phosphorene degradation and is valuable for the development of phosphorene-based materials.
000872925 536__ $$0G:(DE-HGF)POF3-113$$a113 - Methods and Concepts for Material Development (POF3-113)$$cPOF3-113$$fPOF III$$x0
000872925 588__ $$aDataset connected to CrossRef
000872925 7001_ $$0P:(DE-HGF)0$$aWang, Zhiqiang$$b1
000872925 7001_ $$0P:(DE-HGF)0$$aZhao, Feipeng$$b2
000872925 7001_ $$0P:(DE-HGF)0$$aLi, Minsi$$b3
000872925 7001_ $$0P:(DE-HGF)0$$aGao, Xuejie$$b4
000872925 7001_ $$0P:(DE-HGF)0$$aZhao, Yang$$b5
000872925 7001_ $$0P:(DE-Juel1)179392$$aWang, Jian$$b6
000872925 7001_ $$0P:(DE-HGF)0$$aZhou, Jigang$$b7
000872925 7001_ $$0P:(DE-HGF)0$$aHu, Yongfeng$$b8
000872925 7001_ $$0P:(DE-HGF)0$$aXiao, Qunfeng$$b9
000872925 7001_ $$0P:(DE-HGF)0$$aCui, Xiaoyu$$b10
000872925 7001_ $$0P:(DE-HGF)0$$aEslamibidgoli, Mohammad Javad$$b11
000872925 7001_ $$0P:(DE-HGF)0$$aEikerling, Michael. H.$$b12
000872925 7001_ $$0P:(DE-HGF)0$$aLi, Ruying$$b13
000872925 7001_ $$0P:(DE-HGF)0$$aBrandys, Frank$$b14
000872925 7001_ $$0P:(DE-HGF)0$$aDivigalpitiya, Ranjith$$b15
000872925 7001_ $$0P:(DE-HGF)0$$aSham, Tsun-Kong$$b16$$eCorresponding author
000872925 7001_ $$0P:(DE-HGF)0$$aSun, Xueliang$$b17$$eCorresponding author
000872925 773__ $$0PERI:(DE-600)1500399-1$$a10.1021/acs.chemmater.9b04811$$gp. acs.chemmater.9b04811$$p1272-1280$$tChemistry of materials$$v32$$x1520-5002$$y2020
000872925 8564_ $$uhttps://juser.fz-juelich.de/record/872925/files/Phosphorene%20Degradation%20-%20Post%20Print.pdf$$yPublished on 2020-01-15. Available in OpenAccess from 2021-01-15.
000872925 8564_ $$uhttps://juser.fz-juelich.de/record/872925/files/acs.chemmater.9b04811.pdf$$yRestricted
000872925 8564_ $$uhttps://juser.fz-juelich.de/record/872925/files/acs.chemmater.9b04811.pdf?subformat=pdfa$$xpdfa$$yRestricted
000872925 909CO $$ooai:juser.fz-juelich.de:872925$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000872925 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich$$b11$$kFZJ
000872925 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-HGF)0$$aForschungszentrum Jülich$$b12$$kFZJ
000872925 9131_ $$0G:(DE-HGF)POF3-113$$1G:(DE-HGF)POF3-110$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lEnergieeffizienz, Materialien und Ressourcen$$vMethods and Concepts for Material Development$$x0
000872925 9141_ $$y2020
000872925 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000872925 915__ $$0StatID:(DE-HGF)1160$$2StatID$$aDBCoverage$$bCurrent Contents - Engineering, Computing and Technology
000872925 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000872925 915__ $$0StatID:(DE-HGF)0530$$2StatID$$aEmbargoed OpenAccess
000872925 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bCHEM MATER : 2017
000872925 915__ $$0StatID:(DE-HGF)9905$$2StatID$$aIF >= 5$$bCHEM MATER : 2017
000872925 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000872925 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000872925 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000872925 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000872925 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000872925 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000872925 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000872925 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List
000872925 920__ $$lyes
000872925 9201_ $$0I:(DE-Juel1)IEK-13-20190226$$kIEK-13$$lIEK-13$$x0
000872925 9801_ $$aFullTexts
000872925 980__ $$ajournal
000872925 980__ $$aVDB
000872925 980__ $$aUNRESTRICTED
000872925 980__ $$aI:(DE-Juel1)IEK-13-20190226
000872925 981__ $$aI:(DE-Juel1)IET-3-20190226