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@PHDTHESIS{Oelmann:873300,
author = {Oelmann, Jannis},
title = {{Q}uantitative {U}ntersuchung des {L}aserablationsprozesses
mittels {K}ombination von optischer {S}pektroskopie und
{M}assenspektrometrie},
volume = {486},
school = {Universität Bochum},
type = {Dr.},
address = {Jülich},
publisher = {Forschungszentrum Jülich GmbH Zentralbibliothek, Verlag},
reportid = {FZJ-2020-00618},
isbn = {978-3-95806-453-9},
series = {Schriften des Forschungszentrums Jülich Reihe Energie $\&$
Umwelt / Energy $\&$ Environment},
pages = {X, 141 S.},
year = {2020},
note = {Universität Bochum, Diss., 2019},
abstract = {This dissertation assesses the process of laser-induced
ablation using picosecond laser pulses by applying it to
different materials. The introduction reviews the
theoretical background of the different ablation mechanisms,
which are classified according to the used laser parameters.
Following that, the ablation is characterized by employing
various experimental methods: the crater formation resulting
from successive ablation and the material-depending ablation
rates are determined by analyzing the crater structures.
Moreover, an experimental setup for the study of
laser-induced ablation in vacuum, which has been built in
the course of this work, is presented. This setup enables
the simultaneous appliance of mass spectrometry and
complementary optical spectroscopy. The analyses of a thin
film solar cell and a C/Ti/Mo-layer structure demonstrate
that depth-resolved sample characterization is possible with
laser-induced ablation using picosecond pulse durations.
Results show that the ablation rates within one sample layer
are proportional to the applied pulse energy. In spite of
the short pulse duration of τ$_{L}$ = 35 ps, thermal
effects are observed in the ablation process: the crater
size depends on the laser pulse energy and material is
redeposited around the crater in the laser-induced ablation
process. Laser parameters like pulse energy and diameter are
optimized for the determination of hydrogen content in
fusion-relevant materials via a residual gas analysis and a
simultaneously performed laser-induced breakdown
spectroscopy. An investigation of the laser-induced
fragmentation of an amorphous hydrogenated carbon layer
(a–C:H) shows that one third of the total hydrogen content
is found in hydrocarbons after ablation. This needs to be
included in a quantitative sample analysis. For the first
time, the depth-resolved hydrogen content in graphite tiles,
which were exposed in the fusion test facility Wendelstein
7-X, could be measured quantitatively in ex-situ analysis.
The integrated signals show good agreement with thermal
desorption spectroscopy measurements. Aiming at applying the
developed measurement technique in a future fusion reactor,
first results of deuterium retention analyses in graphite
and tungsten are presented. These show particle densities in
the order of 10$^{19}$ $^{D}$ $^{Atome/_{cm}}$ $^{3}$
vorgestellt.},
cin = {IEK-4},
cid = {I:(DE-Juel1)IEK-4-20101013},
pnm = {174 - Plasma-Wall-Interaction (POF3-174)},
pid = {G:(DE-HGF)POF3-174},
typ = {PUB:(DE-HGF)3 / PUB:(DE-HGF)11},
urn = {urn:nbn:de:0001-2020102057},
url = {https://juser.fz-juelich.de/record/873300},
}