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000873528 1001_ $$0P:(DE-Juel1)166277$$aRolletter, Michael$$b0$$ufzj
000873528 245__ $$aThe absorption spectrum and absolute absorption cross sections of acetylperoxy radicals, CH3C(O)O2 in the near IR
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000873528 520__ $$aThe Ã- electronic transition of acetylperoxy radicals (CH3C(O)O2) in the near-infrared was measured at 67hPa synthetic air in the spectral ranges from 6094 cm−1 to 6180 cm−1 and 6420 cm−1 to 6600 cm−1. CH3C(O)O2 radicals were generated by the pulsed photolysis of a acetaldehyde/Cl2/O2 mixture at 351 nm and subsequently measured by time-resolved continuous-wave cavity ring-down spectroscopy (cw-CRDS). The absorption cross sections of eight discrete absorption lines were determined relative to the absorption cross section of HO2, which has previously been reported. The strongest absorption cross section was found at 6510.73 cm−1 and was determined to be (4.9 ± 2.5) × 10−20 cm2.
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000873528 7001_ $$0P:(DE-HGF)0$$aAssaf, Emmanuel$$b1
000873528 7001_ $$0P:(DE-HGF)0$$aAssali, Mohamed$$b2
000873528 7001_ $$0P:(DE-Juel1)7363$$aFuchs, Hendrik$$b3$$eCorresponding author$$ufzj
000873528 7001_ $$0P:(DE-HGF)0$$aFittschen, Christa$$b4$$eCorresponding author
000873528 773__ $$0PERI:(DE-600)1491916-3$$a10.1016/j.jqsrt.2020.106877$$gVol. 245, p. 106877 -$$p106877 -$$tJournal of quantitative spectroscopy & radiative transfer$$v245$$x0022-4073$$y2020
000873528 8564_ $$uhttps://juser.fz-juelich.de/record/873528/files/Rolletter_JQSRT_2020.pdf$$yPublished on 2020-02-03. Available in OpenAccess from 2022-02-03.
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