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@ARTICLE{Rolletter:873528,
author = {Rolletter, Michael and Assaf, Emmanuel and Assali, Mohamed
and Fuchs, Hendrik and Fittschen, Christa},
title = {{T}he absorption spectrum and absolute absorption cross
sections of acetylperoxy radicals, {CH}3{C}({O}){O}2 in the
near {IR}},
journal = {Journal of quantitative spectroscopy $\&$ radiative
transfer},
volume = {245},
issn = {0022-4073},
address = {New York, NY [u.a.]},
publisher = {Elsevier},
reportid = {FZJ-2020-00796},
pages = {106877 -},
year = {2020},
abstract = {The Ã- electronic transition of acetylperoxy radicals
(CH3C(O)O2) in the near-infrared was measured at 67hPa
synthetic air in the spectral ranges from 6094 cm−1 to
6180 cm−1 and 6420 cm−1 to 6600 cm−1. CH3C(O)O2
radicals were generated by the pulsed photolysis of a
acetaldehyde/Cl2/O2 mixture at 351 nm and subsequently
measured by time-resolved continuous-wave cavity ring-down
spectroscopy (cw-CRDS). The absorption cross sections of
eight discrete absorption lines were determined relative to
the absorption cross section of HO2, which has previously
been reported. The strongest absorption cross section was
found at 6510.73 cm−1 and was determined to be
(4.9 ± 2.5) × 10−20 cm2.},
cin = {IEK-8},
ddc = {530},
cid = {I:(DE-Juel1)IEK-8-20101013},
pnm = {243 - Tropospheric trace substances and their
transformation processes (POF3-243)},
pid = {G:(DE-HGF)POF3-243},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000534641000022},
doi = {10.1016/j.jqsrt.2020.106877},
url = {https://juser.fz-juelich.de/record/873528},
}