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@ARTICLE{Qiu:873971,
author = {Qiu, Depeng and Duan, Weiyuan and Lambertz, Andreas and
Bittkau, Karsten and Steuter, Paul and Liu, Yong and Gad,
Alaaeldin and Pomaska, Manuel and Rau, Uwe and Ding,
Kaining},
title = {{F}ront contact optimization for rear-junction {SHJ} solar
cells with ultra-thin n-type nanocrystalline silicon oxide},
journal = {Solar energy materials $\&$ solar cells},
volume = {209},
issn = {0927-0248},
address = {Amsterdam [u.a.]},
publisher = {NH, Elsevier},
reportid = {FZJ-2020-01134},
pages = {110471},
year = {2020},
abstract = {In this work, ultra-thin n-type hydrogenated
nanocrystalline silicon oxide [(nc-SiOx:H (n)] film was used
to replace amorphous silicon [a-Si:H (n)] as electron
transport layer (ETL) in rear-junction silicon
heterojunction (SHJ) solar cell to reduce front parasitic
absorption. The contact resistivity between the transparent
conductive oxide (TCO) and ultra-thin ETL interface plays an
important role on the cell performance. A nanocrystalline
silicon (nc-Si:H) contact or seed layer was introduced in
the solar cell with ultra-thin nc-SiOx:H and the impact of
the nc-Si:H thickness on the cell performance was
investigated. To demonstrate scalability, bifacial solar
cells with 10 nm ETL were fabricated on the M2 (244 cm2)
wafer. The best cell performance is obtained by the solar
cell with 5 nm nc-SiOx:H (n) and 5 nm nc-Si:H (n) contact
layer and it exhibits open-circuit voltage (Voc) of 738 mV,
fill factor (FF) of $80.4\%,$ short-circuit current density
(Jsc) of 39.0 mA/cm2 and power conversion efficiency (η) of
$23.1\%$ on M2 wafer. Compared to the one with nc-SiOx:H
(n), an increase of $3\%abs$ of FF and $0.5\%abs$ of η and
lower front contact resistivity is demonstrated for the
solar cells with nc-Si:H (n) / nc-SiOx:H (n) double layer,
which is caused by the lower energy barrier for electrons,
according to the band diagram calculated by the AFORS-HET
simulator. A simulation on the solar cell optical and
electrical losses was done by the Quokka 3 simulator and
shows much lower electrical transport loss and a bit higher
front surface transmission loss for the one with double
layer than nc-SiOx:H (n) single layer.},
cin = {IEK-5},
ddc = {620},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000525756800014},
doi = {10.1016/j.solmat.2020.110471},
url = {https://juser.fz-juelich.de/record/873971},
}