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@ARTICLE{Grimm:874045,
      author       = {Grimm, Fabian and Menzler, Norbert H. and Guillon, Olivier},
      title        = {{S}election of cathode materials for forsterite supported
                      solid oxide fuel cells – {P}art {I}: {M}aterials
                      interactions},
      journal      = {Journal of power sources},
      volume       = {451},
      issn         = {0378-7753},
      address      = {New York, NY [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2020-01200},
      pages        = {227607 -},
      year         = {2020},
      abstract     = {An inert-supported cell (ISC) was developed by Bosch with
                      the aim of lowering the manufacturing costs of SOFCs and
                      thus increasing their marketability and prolonging their
                      lifetime. This ISC concept uses forsterite, a magnesium
                      silicate doped with Zn and Ca, as support material. The cell
                      can be described as air side inert-supported cell, since
                      forsterite faces the air compartment.Forsterite was chosen
                      as a support material, as it is abundant and therefore
                      relatively inexpensive. All functional layers are
                      subsequently applied and co-sintered at T < 1300 °C to
                      further reduce cell manufacturing costs.At present, LSM is
                      used as a cathode. However, the performance of the cell is
                      drastically reduced due to the formation of a Zn–Mn spinel
                      at the triple-phase boundaries during co-firing.Based on
                      these findings, seven different cathodes were synthesized to
                      identify a cathode that is less reactive with forsterite. In
                      order to investigate their reactivity, different types of
                      samples were prepared: mixed pellets, double-layered pellets
                      and screen-printed cathode inks on forsterite green
                      substrates. These samples and their cross sections were then
                      investigated by using XRD, SEM, EDX, and WDX. Their
                      reactivity was as follows (ascending order): LSFM > LSF >
                      LSC > PSCF > LSCF > LCCF.},
      cin          = {IEK-1},
      ddc          = {620},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
                      (SOFC-20140602)},
      pid          = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000518874300065},
      doi          = {10.1016/j.jpowsour.2019.227607},
      url          = {https://juser.fz-juelich.de/record/874045},
}