000874162 001__ 874162
000874162 005__ 20240610115420.0
000874162 0247_ $$2doi$$a10.1002/marc.201900422
000874162 0247_ $$2ISSN$$a0173-2803
000874162 0247_ $$2ISSN$$a1022-1336
000874162 0247_ $$2ISSN$$a1521-3927
000874162 0247_ $$2Handle$$a2128/24660
000874162 0247_ $$2pmid$$apmid:31736176
000874162 0247_ $$2WOS$$aWOS:000496821400001
000874162 037__ $$aFZJ-2020-01262
000874162 082__ $$a540
000874162 1001_ $$0P:(DE-HGF)0$$aWypysek, Sarah K.$$b0
000874162 245__ $$aTailoring the Cavity of Hollow Polyelectrolyte Microgels
000874162 260__ $$aWeinheim$$bWiley-VCH$$c2020
000874162 3367_ $$2DRIVER$$aarticle
000874162 3367_ $$2DataCite$$aOutput Types/Journal article
000874162 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1586244492_13716
000874162 3367_ $$2BibTeX$$aARTICLE
000874162 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000874162 3367_ $$00$$2EndNote$$aJournal Article
000874162 520__ $$aThe authors demonstrate how the size and structure of the cavity of hollow charged microgels may be controlled by varying pH and ionic strength. Hollow charged microgels based on N‐isopropylacrylamide with ionizable co‐monomers (itaconic acid) combine advanced structure with enhanced responsiveness to external stimuli. Structural advantages accrue from the increased surface area provided by the extra internal surface. Extreme sensitivity to pH and ionic strength due to ionizable moieties in the polymer network differentiates these soft colloidal particles from their uncharged counterparts, which sustain a hollow structure only at cross‐link densities sufficiently high that stimuli sensitivity is reduced. Using small‐angle neutron and light scattering, increased swelling of the network in the charged state accompanied by an expanded internal cavity is observed. Upon addition of salt, the external fuzziness of the microgel surface diminishes while the internal fuzziness grows. These structural changes are interpreted via Poisson–Boltzmann theory in the cell model.
000874162 536__ $$0G:(DE-HGF)POF3-899$$a899 - ohne Topic (POF3-899)$$cPOF3-899$$fPOF III$$x0
000874162 536__ $$0G:(DE-HGF)POF3-6G15$$a6G15 - FRM II / MLZ (POF3-6G15)$$cPOF3-6G15$$fPOF III$$x1
000874162 536__ $$0G:(DE-HGF)POF3-6G4$$a6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)$$cPOF3-623$$fPOF III$$x2
000874162 536__ $$0G:(DE-Juel1)IHRS-BioSoft-20061101$$aIHRS-BioSoft - International Helmholtz Research School of Biophysics and Soft Matter (IHRS-BioSoft-20061101)$$cIHRS-BioSoft-20061101$$x3
000874162 588__ $$aDataset connected to CrossRef
000874162 65027 $$0V:(DE-MLZ)SciArea-210$$2V:(DE-HGF)$$aSoft Condensed Matter$$x0
000874162 65017 $$0V:(DE-MLZ)GC-1602-2016$$2V:(DE-HGF)$$aPolymers, Soft Nano Particles and  Proteins$$x0
000874162 693__ $$0EXP:(DE-MLZ)KWS2-20140101$$1EXP:(DE-MLZ)FRMII-20140101$$5EXP:(DE-MLZ)KWS2-20140101$$6EXP:(DE-MLZ)NL3ao-20140101$$aForschungs-Neutronenquelle Heinz Maier-Leibnitz $$eKWS-2: Small angle scattering diffractometer$$fNL3ao$$x0
000874162 7001_ $$0P:(DE-HGF)0$$aScotti, Andrea$$b1$$eCorresponding author
000874162 7001_ $$0P:(DE-HGF)0$$aAlziyadi, Mohammed O.$$b2
000874162 7001_ $$0P:(DE-Juel1)180875$$aPotemkin, Grigory$$b3$$ufzj
000874162 7001_ $$0P:(DE-HGF)0$$aDenton, Alan R.$$b4
000874162 7001_ $$0P:(DE-Juel1)IHRS-BioSoft-140012$$aRichtering, Walter$$b5$$eCorresponding author
000874162 773__ $$0PERI:(DE-600)1475027-2$$a10.1002/marc.201900422$$gVol. 41, no. 1, p. 1900422 -$$n1$$p1900422 -$$tMacromolecular rapid communications$$v41$$x1521-3927$$y2020
000874162 8564_ $$uhttps://juser.fz-juelich.de/record/874162/files/marc.201900422-2.pdf$$yOpenAccess
000874162 8564_ $$uhttps://juser.fz-juelich.de/record/874162/files/marc.201900422-2.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000874162 909CO $$ooai:juser.fz-juelich.de:874162$$pdnbdelivery$$pVDB$$pVDB:MLZ$$pdriver$$popen_access$$popenaire
000874162 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)180875$$aForschungszentrum Jülich$$b3$$kFZJ
000874162 9101_ $$0I:(DE-HGF)0$$6P:(DE-Juel1)IHRS-BioSoft-140012$$aExternal Institute$$b5$$kExtern
000874162 9131_ $$0G:(DE-HGF)POF3-899$$1G:(DE-HGF)POF3-890$$2G:(DE-HGF)POF3-800$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bProgrammungebundene Forschung$$lohne Programm$$vohne Topic$$x0
000874162 9131_ $$0G:(DE-HGF)POF3-6G15$$1G:(DE-HGF)POF3-6G0$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G15$$aDE-HGF$$bForschungsbereich Materie$$lGroßgeräte: Materie$$vFRM II / MLZ$$x1
000874162 9131_ $$0G:(DE-HGF)POF3-623$$1G:(DE-HGF)POF3-620$$2G:(DE-HGF)POF3-600$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$9G:(DE-HGF)POF3-6G4$$aDE-HGF$$bForschungsbereich Materie$$lVon Materie zu Materialien und Leben$$vFacility topic: Neutrons for Research on Condensed Matter$$x2
000874162 9141_ $$y2020
000874162 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS
000874162 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000874162 915__ $$0StatID:(DE-HGF)0600$$2StatID$$aDBCoverage$$bEbsco Academic Search
000874162 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bMACROMOL RAPID COMM : 2017
000874162 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection
000874162 915__ $$0StatID:(DE-HGF)0110$$2StatID$$aWoS$$bScience Citation Index
000874162 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded
000874162 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5
000874162 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000874162 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bASC
000874162 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences
000874162 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline
000874162 915__ $$0StatID:(DE-HGF)0420$$2StatID$$aNationallizenz
000874162 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List
000874162 920__ $$lyes
000874162 9201_ $$0I:(DE-Juel1)IHRS-BioSoft-20161118$$kIHRS-BioSoft$$lInternational Helmholtz Research School of Biophysics and Soft Matter$$x0
000874162 9201_ $$0I:(DE-Juel1)ICS-2-20110106$$kICS-2$$lTheorie der Weichen Materie und Biophysik$$x1
000874162 9201_ $$0I:(DE-Juel1)JCNS-FRM-II-20110218$$kJCNS-FRM-II$$lJCNS-FRM-II$$x2
000874162 9201_ $$0I:(DE-588b)4597118-3$$kMLZ$$lHeinz Maier-Leibnitz Zentrum$$x3
000874162 9201_ $$0I:(DE-Juel1)PGI-7-20110106$$kPGI-7$$lElektronische Materialien$$x4
000874162 9801_ $$aFullTexts
000874162 980__ $$ajournal
000874162 980__ $$aVDB
000874162 980__ $$aI:(DE-Juel1)IHRS-BioSoft-20161118
000874162 980__ $$aI:(DE-Juel1)ICS-2-20110106
000874162 980__ $$aI:(DE-Juel1)JCNS-FRM-II-20110218
000874162 980__ $$aI:(DE-588b)4597118-3
000874162 980__ $$aI:(DE-Juel1)PGI-7-20110106
000874162 980__ $$aUNRESTRICTED
000874162 981__ $$aI:(DE-Juel1)IBI-5-20200312
000874162 981__ $$aI:(DE-Juel1)IAS-2-20090406