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@ARTICLE{Kerscher:874327,
author = {Kerscher, Michael and Lipfert, Frederik and Frielinghaus,
Henrich},
title = {{E}xploring {H}idden {L}ocal {O}rdering in {M}icroemulsions
with a {W}eak {D}irective {S}econd {O}rder {P}arameter},
journal = {Chemistry Africa},
volume = {3},
issn = {2522-5766},
address = {Cham},
publisher = {Springer International Publishing},
reportid = {FZJ-2020-01375},
pages = {703-709},
year = {2020},
abstract = {So far, the near-surface ordering of microemulsions was
focused on lamellar ordering while the bulk microemulsion
was bicontinuous. In a series of different non-ionic
surfactants the near-surface ordering of microemulsions at a
hydrophilic silicon surface was studied using grazing
incidence small angle neutron scattering. For the surfactant
C8E3, most likely a gyroid structure was found at the
solid–liquid interface, while the more efficient
surfactants find lamellar ordering up to lamellar capillary
condensation. The ranges for near-surface ordering are
deeper than the bulk correlation lengths. These findings
point towards theories that use directional order parameters
that would lead to deeper near-surface ordering than simple
theories with a single scalar order parameter would predict.
Rheology experiments display high viscosities at very low
shear rates and, therefore, support the existence of a
directional order parameter.},
cin = {JCNS-FRM-II / MLZ / JCNS-1},
ddc = {540},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
I:(DE-Juel1)JCNS-1-20110106},
pnm = {6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15) / 6215 - Soft Matter,
Health and Life Sciences (POF3-621)},
pid = {G:(DE-HGF)POF3-6G4 / G:(DE-HGF)POF3-6G15 /
G:(DE-HGF)POF3-6215},
experiment = {EXP:(DE-MLZ)KWS1-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000705288300017},
doi = {10.1007/s42250-020-00126-7},
url = {https://juser.fz-juelich.de/record/874327},
}