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| 001 | 874327 | ||
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| 100 | 1 | _ | |a Kerscher, Michael |0 P:(DE-HGF)0 |b 0 |
| 245 | _ | _ | |a Exploring Hidden Local Ordering in Microemulsions with a Weak Directive Second Order Parameter |
| 260 | _ | _ | |a Cham |c 2020 |b Springer International Publishing |
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| 520 | _ | _ | |a So far, the near-surface ordering of microemulsions was focused on lamellar ordering while the bulk microemulsion was bicontinuous. In a series of different non-ionic surfactants the near-surface ordering of microemulsions at a hydrophilic silicon surface was studied using grazing incidence small angle neutron scattering. For the surfactant C8E3, most likely a gyroid structure was found at the solid–liquid interface, while the more efficient surfactants find lamellar ordering up to lamellar capillary condensation. The ranges for near-surface ordering are deeper than the bulk correlation lengths. These findings point towards theories that use directional order parameters that would lead to deeper near-surface ordering than simple theories with a single scalar order parameter would predict. Rheology experiments display high viscosities at very low shear rates and, therefore, support the existence of a directional order parameter. |
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| 700 | 1 | _ | |a Lipfert, Frederik |0 P:(DE-Juel1)139010 |b 1 |
| 700 | 1 | _ | |a Frielinghaus, Henrich |0 P:(DE-Juel1)130646 |b 2 |e Corresponding author |
| 773 | _ | _ | |a 10.1007/s42250-020-00126-7 |0 PERI:(DE-600)2939117-9 |p 703-709 |t Chemistry Africa |v 3 |y 2020 |x 2522-5766 |
| 856 | 4 | _ | |y OpenAccess |u https://juser.fz-juelich.de/record/874327/files/Kerscher2020_Article_ExploringHiddenLocalOrderingIn.pdf |
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