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| 001 | 874375 | ||
| 005 | 20210130004648.0 | ||
| 024 | 7 | _ | |a 10.1021/acs.jpcc.9b11716 |2 doi |
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| 024 | 7 | _ | |a 1932-7455 |2 ISSN |
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| 037 | _ | _ | |a FZJ-2020-01397 |
| 082 | _ | _ | |a 530 |
| 100 | 1 | _ | |a Mennicken, Max |0 P:(DE-Juel1)168174 |b 0 |u fzj |
| 245 | _ | _ | |a Transport through Redox-Active Ru-Terpyridine Complexes Integrated in Single Nanoparticle Devices |
| 260 | _ | _ | |a Washington, DC |c 2020 |b Soc. |
| 336 | 7 | _ | |a article |2 DRIVER |
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| 520 | _ | _ | |a Transition metal complexes are electrofunctional molecules due to their high conductivity and their intrinsic switching ability involving a metal-to-ligand charge transfer. Here, a method is presented to contact reliably a few to single redox-active Ru-terpyridine complexes in a CMOS compatible nanodevice and preserve their electrical functionality. Using hybrid materials from 14 nm gold nanoparticles (AuNP) and bis-{4′-[4-(mercaptophenyl)-2,2′:6′,2″-terpyridine]}-ruthenium(II) complexes a device size of 302 nm2 inclusive nanoelectrodes is achieved. Moreover, this method bears the opportunity for further downscaling. The Ru-complex AuNP devices show symmetric and asymmetric current versus voltage curves with a hysteretic characteristic in two well separated conductance ranges. By theoretical approximations based on the single-channel Landauer model, the charge transport through the formed double-barrier tunnel junction is thoroughly analyzed and its sensibility to the molecule/metal contact is revealed. It can be verified that tunneling transport through the HOMO is the main transport mechanism while decoherent hopping transport is present to a minor extent. |
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| 700 | 1 | _ | |a Peter, Sophia K. |0 P:(DE-HGF)0 |b 1 |
| 700 | 1 | _ | |a Kaulen, Corinna |0 0000-0003-1194-5192 |b 2 |
| 700 | 1 | _ | |a Simon, Ulrich |0 0000-0002-6118-0573 |b 3 |
| 700 | 1 | _ | |a Karthäuser, Silvia |0 P:(DE-Juel1)130751 |b 4 |e Corresponding author |
| 773 | _ | _ | |a 10.1021/acs.jpcc.9b11716 |g Vol. 124, no. 8, p. 4881 - 4889 |0 PERI:(DE-600)2256522-X |n 8 |p 4881 - 4889 |t The journal of physical chemistry |v 124 |y 2020 |x 1932-7455 |
| 856 | 4 | _ | |y Published on 2020-02-05. Available in OpenAccess from 2021-02-05. |u https://juser.fz-juelich.de/record/874375/files/Ru_Switch_SuppInfo_rev.pdf |
| 856 | 4 | _ | |y Published on 2020-02-05. Available in OpenAccess from 2021-02-05. |u https://juser.fz-juelich.de/record/874375/files/Ru_Switch_rev.pdf |
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| 856 | 4 | _ | |y Published on 2020-02-05. Available in OpenAccess from 2021-02-05. |x pdfa |u https://juser.fz-juelich.de/record/874375/files/Ru_Switch_SuppInfo_rev.pdf?subformat=pdfa |
| 856 | 4 | _ | |y Published on 2020-02-05. Available in OpenAccess from 2021-02-05. |x pdfa |u https://juser.fz-juelich.de/record/874375/files/Ru_Switch_rev.pdf?subformat=pdfa |
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