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@ARTICLE{Hutter:874431,
author = {Hutter, Eline M. and Kirchartz, Thomas and Ehrler, Bruno
and Cahen, David and von Hauff, Elizabeth},
title = {{P}itfalls and prospects of optical spectroscopy to
characterize perovskite-transport layer interfaces},
journal = {Applied physics letters},
volume = {116},
number = {10},
issn = {1077-3118},
address = {Melville, NY},
publisher = {American Inst. of Physics},
reportid = {FZJ-2020-01441},
pages = {100501 -},
year = {2020},
abstract = {Perovskite photovoltaics has witnessed an unprecedented
increase in power conversion efficiency over the last
decade. The choice of transport layers, through which
photo-generated electrons and holes are transported to
electrodes, is a crucial factor for further improving both
the device performance and stability. In this perspective,
we critically examine the application of optical
spectroscopy to characterize the quality of the transport
layer-perovskite interface. We highlight the power of
complementary studies that use both continuous wave and
time-resolved photoluminescence to understand non-radiative
losses and additional transient spectroscopies for
characterizing the potential for loss-less carrier
extraction at the solar cell interfaces. Based on this
discussion, we make recommendations on how to extrapolate
results from optical measurements to assess the quality of a
transport layer and its impact on solar cell efficiency.The
work of E.M.H. and B.E. is part of the Dutch Research
Council (NWO) and was performed at the research institute
AMOLF. T.K. acknowledges the Helmholtz Association for
funding via the PEROSEED project. D.C acknowledges funding
from the Yotam project and the CNRS-Weizmann collaboration.},
cin = {IEK-5},
ddc = {530},
cid = {I:(DE-Juel1)IEK-5-20101013},
pnm = {121 - Solar cells of the next generation (POF3-121)},
pid = {G:(DE-HGF)POF3-121},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000520099100001},
doi = {10.1063/1.5143121},
url = {https://juser.fz-juelich.de/record/874431},
}