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@ARTICLE{Jin:874642,
author = {Jin, Lei and Zapf, Michael and Stübinger, Martin and Kamp,
Martin and Sing, Michael and Claessen, Ralph and Jia,
Chun-Lin},
title = {{A}tomic‐scale interface structure in domain matching
epitaxial {B}a{B}i{O}$_{3}$ thin films grown on
{S}r{T}i{O}$_{3}$ substrates},
journal = {Physica status solidi / Rapid research letters Rapid
research letters [...]},
volume = {14},
number = {6},
issn = {1862-6270},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2020-01561},
pages = {2000054 -},
year = {2020},
abstract = {The electronic structures of BaBiO3 (BBO) thin films grown
on SrTiO3 substrates are found to be thickness dependent.
The origin of this behavior remains under debate and has
been suggested to be attributed to the structural and
compositional modifications at the BBO/SrTiO3 interface
during the first stage of film growth. Though a wetting
layer with thickness of ≈1 nm has been experimentally
identified at the interface, details on the microstructures
of such a layer and their effect on the subsequent film
growth are lacking so far, particularly at the atomic scale.
Herein, atomic‐resolution scanning transmission electron
microscopy is used to study the interface structure of a
30 nm‐thick BBO film grown on an Nb‐doped SrTiO3 (STO)
substrate through domain matching epitaxy. An interfacial
δ‐Bi2O3 (BO)‐like phase with fluorite structure is
identified, showing a layer‐by‐layer spacing of
≈3.2 Å along the growth direction. The orientation
relationship between the BO‐like phase and surrounding
perovskites (P) is found to be <001>BO||<001>P and
<110>BO||<100>P. The presence of the BO‐like phase results
in two types of interfaces, i.e., a coherent BO/STO and a
semicoherent BBO/BO interface. Thickness variations are
observed in the BO‐like layer, resulting in the formation
of antiphase domains in the BBO films.},
cin = {ER-C-1},
ddc = {530},
cid = {I:(DE-Juel1)ER-C-1-20170209},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000520715600001},
doi = {10.1002/pssr.202000054},
url = {https://juser.fz-juelich.de/record/874642},
}