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@ARTICLE{Liedgens:874920,
author = {Liedgens, Linda and Zimmermann, Jannik and Wäschenbach,
Lucas and Geissel, Fabian and Laporte, Hugo and Gohlke,
Holger and Morgan, Bruce and Deponte, Marcel},
title = {{Q}uantitative assessment of the determinant structural
differences between redox-active and inactive glutaredoxins},
journal = {Nature Communications},
volume = {11},
number = {1},
issn = {2041-1723},
address = {[London]},
publisher = {Nature Publishing Group UK},
reportid = {FZJ-2020-01704},
pages = {1725},
year = {2020},
abstract = {Class I glutaredoxins are enzymatically active,
glutathione-dependent oxidoreductases, whilst class II
glutaredoxins are typically enzymatically inactive, Fe-S
cluster-binding proteins. Enzymatically active glutaredoxins
harbor both a glutathione-scaffold site for reacting with
glutathionylated disulfide substrates and a
glutathione-activator site for reacting with reduced
glutathione. Here, using yeast ScGrx7 as a model protein, we
comprehensively identified and characterized key residues
from four distinct protein regions, as well as the
covalently bound glutathione moiety, and quantified their
contribution to both interaction sites. Additionally, we
developed a redox-sensitive GFP2-based assay, which allowed
the real-time assessment of glutaredoxin structure-function
relationships inside living cells. Finally, we employed this
assay to rapidly screen multiple glutaredoxin mutants,
ultimately enabling us to convert enzymatically active and
inactive glutaredoxins into each other. In summary, we have
gained a comprehensive understanding of the mechanistic
underpinnings of glutaredoxin catalysis and have elucidated
the determinant structural differences between the two main
classes of glutaredoxins.},
cin = {NIC / JSC / IBI-7},
ddc = {500},
cid = {I:(DE-Juel1)NIC-20090406 / I:(DE-Juel1)JSC-20090406 /
I:(DE-Juel1)IBI-7-20200312},
pnm = {511 - Computational Science and Mathematical Methods
(POF3-511) / Forschergruppe Gohlke $(hkf7_20170501)$ /
Targeting spectrin redox switches to regulate the
mechanoproperties of red blood cells $(hdd19_20171101)$},
pid = {G:(DE-HGF)POF3-511 / $G:(DE-Juel1)hkf7_20170501$ /
$G:(DE-Juel1)hdd19_20171101$},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:32265442},
UT = {WOS:000526532500003},
doi = {10.1038/s41467-020-15441-3},
url = {https://juser.fz-juelich.de/record/874920},
}