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@ARTICLE{Noferini:874983,
      author       = {Noferini, Daria and Holderer, Olaf and Frielinghaus,
                      Henrich},
      title        = {{E}ffect of mild nanoscopic confinement on the dynamics of
                      ionic liquids},
      journal      = {Physical chemistry, chemical physics},
      volume       = {22},
      number       = {16},
      issn         = {1463-9084},
      address      = {Cambridge},
      publisher    = {RSC Publ.},
      reportid     = {FZJ-2020-01748},
      pages        = {9046-9052},
      year         = {2020},
      abstract     = {Ionic liquids are molten salts without an additional
                      solvent and are discussed as innovative solvents and
                      electrolytes in chemical processing and electrochemistry. A
                      thorough microscopic understanding of the structure and
                      ionic transport processes is essential for tailored
                      applications. Here, we study the influence of “mild”
                      nanoscopic confinement on the structure and diffusion
                      properties of an ionic liquid, 1-ethyl-3-methylimidazolium
                      acetate, using scattering techniques. The structure is
                      analyzed by X-ray diffraction, while neutron backscattering
                      spectroscopy is used for the study of the diffusion
                      processes in these systems. Interpreting the diffusion
                      processes in terms of a jump-diffusion model allowed us to
                      deduce the confinement effects on the jump length and
                      residence time, both increased at elevated temperatures in
                      confinement. The applied “mild” confinement, which
                      leaves room for 10–25 times the domain spacing, allows us
                      to observe in great detail how the onset of domain
                      distortion decelerates the dynamics},
      cin          = {JCNS-FRM-II / MLZ / JCNS-1},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
                      I:(DE-Juel1)JCNS-1-20110106},
      pnm          = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
                      6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
                      G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)SPHERES-20140101},
      typ          = {PUB:(DE-HGF)16},
      pubmed       = {pmid:32296792},
      UT           = {WOS:000537175100077},
      doi          = {10.1039/C9CP05200C},
      url          = {https://juser.fz-juelich.de/record/874983},
}