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@ARTICLE{Harboe:875101,
      author       = {Harboe, Siri Johanna and Sohn, Yoo Jung and Guillon,
                      Olivier and Menzler, Norbert H.},
      title        = {{I}nvestigation of {LSM}-8{YSZ} cathode within an all
                      ceramic {SOFC}. {P}art {I}: {C}hemical interactions},
      journal      = {Journal of the European Ceramic Society},
      volume       = {40},
      number       = {10},
      issn         = {0955-2219},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier Science},
      reportid     = {FZJ-2020-01804},
      pages        = {3608 - 3617},
      year         = {2020},
      abstract     = {This work focuses on a novel, co-sintered, all-ceramic
                      solid oxide fuel cell (SOFC) concept. The objective is the
                      understanding of interaction and degradation mechanisms of
                      the cathode and current collector layers within the design
                      during co-sintering. Half cells consisting of silicate
                      mechanical support, lanthanum strontium manganite (LSM)
                      current collector, LSM mixed with $8 mol\%$
                      yttria-stabilized zirconia (8YSZ) composite cathode and 8YSZ
                      electrolyte were co-sintered at
                      1150 °C < T < 1250 °C. Crystallographically
                      stable LSM compositions within the design were identified.
                      However, the cathode and silicate/electrolyte interacted by
                      interdiffusion of Zn (gas diffusion) and Mn (solid
                      diffusion), and by the formation of several reaction phases
                      (between silicate and cathode only). Introducing silicate
                      poisoning decreased the electrochemical performance of the
                      cell by around $40\%.$ This is likely due to the formation
                      of the Zn- and Mn-rich phase in the cathode, but may also be
                      caused by a higher ohmic resistance of the current
                      collector.},
      cin          = {IEK-1},
      ddc          = {660},
      cid          = {I:(DE-Juel1)IEK-1-20101013},
      pnm          = {135 - Fuel Cells (POF3-135) / SOFC - Solid Oxide Fuel Cell
                      (SOFC-20140602)},
      pid          = {G:(DE-HGF)POF3-135 / G:(DE-Juel1)SOFC-20140602},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000528298800014},
      doi          = {10.1016/j.jeurceramsoc.2020.02.004},
      url          = {https://juser.fz-juelich.de/record/875101},
}