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@ARTICLE{Kang:877286,
      author       = {Kang, Jia-Jhen and Jung, Florian A. and Ko, Chia-Hsin and
                      Shehu, Kaltrina and Barnsley, Lester C. and Kohler, Fabian
                      and Dietz, Hendrik and Zhao, Junpeng and Pispas, Stergios
                      and Papadakis, Christine M.},
      title        = {{T}hermoresponsive {M}olecular {B}rushes with {P}ropylene
                      {O}xide/{E}thylene {O}xide {C}opolymer {S}ide {C}hains in
                      {A}queous {S}olution},
      journal      = {Macromolecules},
      volume       = {53},
      number       = {10},
      issn         = {1520-5835},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2020-02109},
      pages        = {4068 - 4081},
      year         = {2020},
      abstract     = {The thermoresponsive behavior of two molecular brushes
                      having poly(propylene oxide)–poly(ethylene oxide)
                      copolymer side chains is investigated in aqueous solution,
                      where the side chains have longer contour lengths than the
                      backbone. The brushes differ in the side-chain architecture;
                      they are either a diblock (PbE) or a random copolymer (PrE).
                      For both types of brushes, an overall rodlike shape at room
                      temperature is revealed by cryo-electron microscopy. A
                      polymer-rich central part and a water-rich outer part are
                      identified by small-angle neutron scattering (SANS). Upon
                      heating up to the cloud point, the shell of PbE weakly
                      dehydrates, while the one of PrE severely dehydrates along
                      with a cylinder-to-disk transformation. Moreover, the
                      aggregates formed above the cloud points feature
                      significantly different inner structures: PbE aggregates are
                      composed of strongly interpenetrating brushes, while PrE
                      aggregates consist of loosely packed brushes. These
                      differences indicate the important role of the side-chain
                      architecture in the thermal dehydration behavior and the
                      associated structural changes.},
      cin          = {JCNS-FRM-II / JCNS-1 / MLZ},
      ddc          = {540},
      cid          = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
                      I:(DE-Juel1)JCNS-1-20110106 / I:(DE-588b)4597118-3},
      pnm          = {6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
                      Neutron Research (JCNS) (POF3-623)},
      pid          = {G:(DE-HGF)POF3-6G15 / G:(DE-HGF)POF3-6G4},
      experiment   = {EXP:(DE-MLZ)KWS1-20140101},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000537677300044},
      doi          = {10.1021/acs.macromol.0c00263},
      url          = {https://juser.fz-juelich.de/record/877286},
}