% IMPORTANT: The following is UTF-8 encoded. This means that in the presence
% of non-ASCII characters, it will not work with BibTeX 0.99 or older.
% Instead, you should use an up-to-date BibTeX implementation like “bibtex8” or
% “biber”.
@ARTICLE{Burre:877458,
author = {Burre, Jannik and Bongartz, Dominik and Mitsos, Alexander},
title = {{P}roduction of {O}xymethylene {D}imethyl {E}thers from
{H}ydrogen and {C}arbon {D}ioxide—{P}art {II}: {M}odeling
and {A}nalysis for {OME} 3–5},
journal = {Industrial $\&$ engineering chemistry research},
volume = {58},
number = {14},
issn = {0888-5885},
address = {Columbus, Ohio},
publisher = {American Chemical Society},
reportid = {FZJ-2020-02211},
pages = {5567 - 5578},
year = {2019},
abstract = {Oxymethylene dimethyl ethers (OMEn) have high potential as
diesel fuels or blending components due to their promising
combustion properties and can be produced from hydrogen (H2)
and carbon dioxide (CO2) by combining existing process
concepts. However, such a process chain has not been
analyzed in detail yet, so its performance and bottlenecks
are unknown. In this second part of our two-part article, we
analyze a process chain for production of the longer chain
variant OME3–5 from renewable H2 and green CO2 via
trioxane and OME1. We simulate in Aspen Plus using detailed
thermodynamic models with coupled oligomerization reactions
and rigorous unit operation models. The overall exergy
efficiency of OME3–5 production from H2 and CO2 using
established process concepts is $53\%.$ Therein, the
trioxane process step has the highest losses due to its high
heat demand. Considering a pinch-based heat integration
throughout the entire process chain its total heat demand
can be reduced by $16\%.$ Thus, the exergy efficiency
increases to $54\%.$ This is still significantly lower
compared to the production of other alternative fuels like
OME1, methane, and dimethyl ether. Thus, more efficient
processes, e.g., by avoiding trioxane production, are
required},
cin = {IEK-10},
ddc = {660},
cid = {I:(DE-Juel1)IEK-10-20170217},
pnm = {899 - ohne Topic (POF3-899)},
pid = {G:(DE-HGF)POF3-899},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000464769200023},
doi = {10.1021/acs.iecr.8b05577},
url = {https://juser.fz-juelich.de/record/877458},
}