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@ARTICLE{Kotov:877499,
author = {Kotov, Vladislav},
title = {{T}wo-modes approach to the state-to-state vibrational
kinetics of {CO}$_{2}$},
journal = {Journal of physics / B},
volume = {53},
number = {17},
issn = {0022-3700},
address = {Bristol},
publisher = {IOP Publ.},
reportid = {FZJ-2020-02249},
pages = {175104 -},
year = {2020},
abstract = {Two-modes (symmetric-asymmetric) reduction of the CO2
vibrational kinetics has been introduced systematically for
the purpose of the state-to-state modelling. The two-modes
approach is known from the multi-temperature models. Its
basic assumption is that vibrational energy of the CO2
molecule which depends on 4 quantum numbers can be
approximated by a function of only 2 numbers. Subsequently,
vibrational states of CO2 with same quantum numbers of the
effective symmetric and of the asymmetric mode can be
grouped into one combined state. The paper presents the
calculation of the average probabilities of transitions
between combined states based on the
Schwartz-Slawsky-Herzfeld theory. Closed analytical formulas
are derived for vibrational-translational and
vibrational-vibrational transitions.},
cin = {IEK-4},
ddc = {530},
cid = {I:(DE-Juel1)IEK-4-20101013},
pnm = {174 - Plasma-Wall-Interaction (POF3-174)},
pid = {G:(DE-HGF)POF3-174},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000553420700001},
doi = {10.1088/1361-6455/ab9d01},
url = {https://juser.fz-juelich.de/record/877499},
}