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@ARTICLE{Laemont:877538,
author = {Laemont, Andreas and Abednatanzi, Sara and Derakshandeh,
Parviz Gohari and Verbruggen, Florian and Fiset, Erika and
Qin, Qing and Van Daele, Kevin and Meledina, Maria and
Schmidt, Johannes and Oschatz, Martin and Van Der Voort,
Pascal and Rabaey, Korneel and Antonietti, Markus and
Breugelmans, Tom and Leus, Karen},
title = {{C}ovalent triazine framework/carbon nanotube hybrids
enabling selective reduction of {CO} 2 to {CO} at low
overpotential},
journal = {Green chemistry},
volume = {22},
number = {10},
issn = {1463-9270},
address = {Cambridge},
publisher = {RSC},
reportid = {FZJ-2020-02274},
pages = {3095 - 3103},
year = {2020},
abstract = {Electrochemical reduction of CO2 provides a way to generate
base chemicals from an abundant C1-source under mild
conditions, whilst at the same time mitigating CO2
emissions. In this work, a novel class of tailorable, porous
electrocatalysts for this process is proposed. Covalent
triazine frameworks (CTFs) are grown in situ onto
functionalized multiwalled carbon nanotubes. Hydroxyl groups
decorating the surface of the multiwalled carbon nanotubes
facilitate intimate contact between the carbon nanotubes and
CTF, thus promoting efficient electron transfer. The novel
hybrid materials generate CO with a faradaic efficiency up
to $81\%$ at an overpotential of 380 mV. The selectivity of
the electrocatalysts could be linked to the amount of
nitrogen present within the framework.},
cin = {ER-C-2},
ddc = {540},
cid = {I:(DE-Juel1)ER-C-2-20170209},
pnm = {131 - Electrochemical Storage (POF3-131) / ESTEEM3 -
Enabling Science and Technology through European Electron
Microscopy (823717)},
pid = {G:(DE-HGF)POF3-131 / G:(EU-Grant)823717},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000537870500030},
doi = {10.1039/D0GC00090F},
url = {https://juser.fz-juelich.de/record/877538},
}