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@ARTICLE{Pasini:877561,
author = {Pasini, S. and Maccarrone, S. and Székely, N. K. and
Stingaciu, L. R. and Gelissen, A. P. H. and Richtering, W.
and Monkenbusch, M. and Holderer, O.},
title = {{F}luctuation suppression in microgels by polymer
electrolytes},
journal = {Structural dynamics},
volume = {7},
number = {3},
issn = {2329-7778},
address = {Melville, NY},
publisher = {AIP Publishing LLC},
reportid = {FZJ-2020-02286},
pages = {034302 -},
year = {2020},
abstract = {Structural details of thermoresponsive, cationically
poly(N-iso-propylacrylamide-co-methacrylamido propyl
trimethyl ammonium chloride) microgels and the influence of
the anionic electrolyte polystyrene sulfonate (PSS) on the
internal structure and dynamics of the cationic microgels
have been studied with a combination of small angle neutron
scattering (SANS) and neutron spin echo (NSE) spectroscopy.
While SANS can yield information on the overall size of the
particles and on the typical correlation length inside the
particles, studying the segmental polymer dynamics with NSE
gives access to more internal details, which only appear due
to their effect on the polymer motion. The segmental
dynamics of the microgels studied in this paper is to a
large extent suppressed by the PSS additive. Possible
scenarios of the influence of the polyanions on the microgel
structure and dynamics are discussed.},
cin = {JCNS-FRM-II / MLZ / JCNS-1 / JCNS-SNS},
ddc = {500},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 / I:(DE-588b)4597118-3 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-SNS-20110128},
pnm = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
6G15 - FRM II / MLZ (POF3-6G15) / 6G4 - Jülich Centre for
Neutron Research (JCNS) (POF3-623)},
pid = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G15 /
G:(DE-HGF)POF3-6G4},
experiment = {EXP:(DE-MLZ)KWS2-20140101 / EXP:(DE-Juel1)SNS-NSE-20150203
/ EXP:(DE-MLZ)J-NSE-20140101},
typ = {PUB:(DE-HGF)16},
pubmed = {pmid:32566697},
UT = {WOS:000542378100001},
doi = {10.1063/4.0000014},
url = {https://juser.fz-juelich.de/record/877561},
}