TY  - JOUR
AU  - Qiu, Kaifu
AU  - Pomaska, Manuel
AU  - Li, Shenghao
AU  - Lambertz, Andreas
AU  - Duan, Weiyuan
AU  - Gad, Alaaeldin
AU  - Geitner, Matthias
AU  - Brugger, Jana
AU  - Liang, Zongcun
AU  - Shen, Hui
AU  - Finger, Friedhelm
AU  - Rau, Uwe
AU  - Ding, Kaining
TI  - Development of Conductive SiC x :H as a New Hydrogenation Technique for Tunnel Oxide Passivating Contacts
JO  - ACS applied materials & interfaces
VL  - 20
SN  - 1944-8252
CY  - Washington, DC
PB  - Soc.
M1  - FZJ-2020-02403
SP  - 29986–29992
PY  - 2020
AB  - Conductive hydrogenated silicon carbide (SiCx:H) is discovered as a promising hydrogenation material for tunnel oxide passivating contacts (TOPCon) solar cells. The proposed SiCx:H layer enables a good passivation quality and features a good electrical conductivity, which eliminates the need of etching back of SiNx:H and indium tin oxide (ITO)/Ag deposition for metallization and reduces the number of process steps. The SiCx:H is deposited by hot wire chemical vapor deposition (HWCVD) and the filament temperature (Tf) during deposition is systematically investigated. Via tuning the SiCx:H layer, implied open-circuit voltages (iVoc) up to 742 ± 0.5 mV and a contact resistivity (ρc) of 21.1 ± 5.4 mΩ·cm2 is achieved using SiCx:H on top of poly-Si(n)/SiOx/c-Si(n) stack at Tf of 2000 °C. Electrochemical capacitance–voltage (ECV) and secondary ion mass spectrometry (SIMS) measurements were conducted to investigate the passivation mechanism. Results show that the hydrogenation at the SiOx/c-Si(n) interface is responsible for the high passivation quality. To assess its validity, the TOPCon stack was incorporated as rear electron selective-contact in a proof-of-concept n-type solar cells featuring ITO/a-Si:H(p)/a-Si:H(i) as front hole selective-contact, which demonstrates a conversion efficiency up to 21.4%, a noticeable open-circuit voltage (Voc) of 724 mV and a fill factor (FF) of 80%.
LB  - PUB:(DE-HGF)16
C6  - 32501671
UR  - <Go to ISI:>//WOS:000546698600111
DO  - DOI:10.1021/acsami.0c06637
UR  - https://juser.fz-juelich.de/record/877693
ER  -