000877820 001__ 877820
000877820 005__ 20220930130244.0
000877820 0247_ $$2doi$$a10.1038/s42004-020-0327-9
000877820 0247_ $$2Handle$$a2128/25434
000877820 0247_ $$2altmetric$$aaltmetric:86885763
000877820 0247_ $$2WOS$$aWOS:000555461800001
000877820 037__ $$aFZJ-2020-02459
000877820 082__ $$a540
000877820 1001_ $$0P:(DE-Juel1)166560$$aSmekhova, Alevtina$$b0
000877820 245__ $$aIntramolecular crossover from unconventional diamagnetism to paramagnetism of palladium ions probed by soft X-ray magnetic circular dichroism
000877820 260__ $$a[London]$$bMacmillan Publishers Limited, part of Springer Nature$$c2020
000877820 3367_ $$2DRIVER$$aarticle
000877820 3367_ $$2DataCite$$aOutput Types/Journal article
000877820 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1596544071_5108
000877820 3367_ $$2BibTeX$$aARTICLE
000877820 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000877820 3367_ $$00$$2EndNote$$aJournal Article
000877820 520__ $$aThe case of palladium(II) ions in molecular polyoxopalladates highlights the importance of accounting not only for nearest neighbour atoms or ions in order to understand, model or predict magnetic characteristics. Here, using site-specific soft X-ray magnetic circular dichroism (XMCD), the effects of different bond lengths, delocalization of 4d electrons, and 4d spin-orbit coupling on the electronic and magnetic properties are investigated and three different states identified: Conventional diamagnetism in a square-planar O4 coordination environment, paramagnetism caused by four additional out-of-plane oxygen anions, and an unusual diamagnetic state in the diamagnetic/paramagnetic crossover region modified by significant mixing of states and facilitated by the substantial 4d spin-orbit coupling. The two diamagnetic states can be distinguished by characteristic XMCD fine structures, thereby overcoming the common limitation of XMCD to ferro-/ferrimagnetic and paramagnetic materials in external magnetic fields. The qualitative interpretation of the results is corroborated by simulations based on charge transfer multiplet calculations and density functional theory results.
000877820 536__ $$0G:(DE-HGF)POF3-522$$a522 - Controlling Spin-Based Phenomena (POF3-522)$$cPOF3-522$$fPOF III$$x0
000877820 588__ $$aDataset connected to CrossRef
000877820 7001_ $$0P:(DE-HGF)0$$aSchmitz, Detlef$$b1
000877820 7001_ $$0P:(DE-Juel1)157892$$aIzarova, Natalya V.$$b2$$ufzj
000877820 7001_ $$0P:(DE-Juel1)166520$$aStuckart, Maria$$b3
000877820 7001_ $$0P:(DE-Juel1)170029$$aShams, S. Fatemeh$$b4
000877820 7001_ $$0P:(DE-HGF)0$$aSiemensmeyer, Konrad$$b5
000877820 7001_ $$0P:(DE-HGF)0$$ade Groot, Frank M. F.$$b6
000877820 7001_ $$0P:(DE-Juel1)130782$$aKögerler, Paul$$b7
000877820 7001_ $$0P:(DE-Juel1)162347$$aSchmitz-Antoniak, Carolin$$b8$$eCorresponding author
000877820 773__ $$0PERI:(DE-600)2929562-2$$a10.1038/s42004-020-0327-9$$gVol. 3, no. 1, p. 96$$n1$$p96$$tCommunications chemistry$$v3$$x2399-3669$$y2020
000877820 8564_ $$uhttps://juser.fz-juelich.de/record/877820/files/Invoice_2676192631.pdf
000877820 8564_ $$uhttps://juser.fz-juelich.de/record/877820/files/Invoice_2676192631.pdf?subformat=pdfa$$xpdfa
000877820 8564_ $$uhttps://juser.fz-juelich.de/record/877820/files/s42004-020-0327-9.pdf$$yOpenAccess
000877820 8564_ $$uhttps://juser.fz-juelich.de/record/877820/files/s42004-020-0327-9.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000877820 8767_ $$82676192631$$92020-07-16$$d2020-08-05$$eAPC$$jZahlung erfolgt$$pCOMMSCHEM-19-0296B$$zBelegnr. 1200155332, vorher falsche Rng: 2676184440
000877820 909CO $$ooai:juser.fz-juelich.de:877820$$popenCost$$pVDB$$pdriver$$pOpenAPC$$popen_access$$popenaire$$pdnbdelivery
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166560$$aForschungszentrum Jülich$$b0$$kFZJ
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)157892$$aForschungszentrum Jülich$$b2$$kFZJ
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)166520$$aForschungszentrum Jülich$$b3$$kFZJ
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)170029$$aForschungszentrum Jülich$$b4$$kFZJ
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)130782$$aForschungszentrum Jülich$$b7$$kFZJ
000877820 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)162347$$aForschungszentrum Jülich$$b8$$kFZJ
000877820 9131_ $$0G:(DE-HGF)POF3-522$$1G:(DE-HGF)POF3-520$$2G:(DE-HGF)POF3-500$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bKey Technologies$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Spin-Based Phenomena$$x0
000877820 9141_ $$y2020
000877820 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-01-11
000877820 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000877820 915__ $$0StatID:(DE-HGF)0112$$2StatID$$aWoS$$bEmerging Sources Citation Index$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0700$$2StatID$$aFees$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000877820 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Blind peer review$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0561$$2StatID$$aArticle Processing Charges$$f2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-01-11
000877820 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-01-11
000877820 9201_ $$0I:(DE-Juel1)PGI-6-20110106$$kPGI-6$$lElektronische Eigenschaften$$x0
000877820 980__ $$ajournal
000877820 980__ $$aVDB
000877820 980__ $$aUNRESTRICTED
000877820 980__ $$aI:(DE-Juel1)PGI-6-20110106
000877820 980__ $$aAPC
000877820 9801_ $$aAPC
000877820 9801_ $$aFullTexts