TY  - JOUR
AU  - Nerl, Hannah C.
AU  - Pokle, Anuj
AU  - Jones, Lewys
AU  - Müller‐Caspary, Knut
AU  - Bos, Karel H. W.
AU  - Downing, Clive
AU  - McCarthy, Eoin K.
AU  - Gauquelin, Nicolas
AU  - Ramasse, Quentin M.
AU  - Lobato, Ivan
AU  - Daly, Dermot
AU  - Idrobo, Juan Carlos
AU  - Van Aert, Sandra
AU  - Van Tendeloo, Gustaaf
AU  - Sanvito, Stefano
AU  - Coleman, Jonathan N.
AU  - Cucinotta, Clotilde S.
AU  - Nicolosi, Valeria
TI  - Self‐Assembly of Atomically Thin Chiral Copper Heterostructures Templated by Black Phosphorus
JO  - Advanced functional materials
VL  - 29
IS  - 37
SN  - 1616-3028
CY  - Weinheim
PB  - Wiley-VCH
M1  - FZJ-2020-02743
SP  - 1903120
PY  - 2019
AB  - The fabrication of 2D systems for electronic devices is not straightforward, with top‐down low‐yield methods often employed leading to irregular nanostructures and lower quality devices. Here, a simple and reproducible method to trigger self‐assembly of arrays of high aspect‐ratio chiral copper heterostructures templated by the structural anisotropy in black phosphorus (BP) nanosheets is presented. Using quantitative atomic resolution aberration‐corrected scanning transmission electron microscopy imaging, in situ heating transmission electron microscopy and electron energy‐loss spectroscopy arrays of heterostructures forming at speeds exceeding 100 nm s−1 and displaying long‐range order over micrometers are observed. The controlled instigation of the self‐assembly of the Cu heterostructures embedded in BP is achieved using conventional electron beam lithography combined with site specific placement of Cu nanoparticles. Density functional theory calculations are used to investigate the atomic structure and suggest a metallic nature of the Cu heterostructures grown in BP. The findings of this new hybrid material with unique dimensionality, chirality, and metallic nature and its triggered self‐assembly open new and exciting opportunities for next generation, self‐assembling devices.
LB  - PUB:(DE-HGF)16
UR  - <Go to ISI:>//WOS:000478478400001
DO  - DOI:10.1002/adfm.201903120
UR  - https://juser.fz-juelich.de/record/878280
ER  -