000878318 001__ 878318
000878318 005__ 20230505130535.0
000878318 0247_ $$2doi$$a10.3762/bjnano.10.169
000878318 0247_ $$2Handle$$a2128/25453
000878318 0247_ $$2altmetric$$aaltmetric:65206622
000878318 0247_ $$2pmid$$apmid:31501745
000878318 0247_ $$2WOS$$aWOS:000482478100001
000878318 037__ $$aFZJ-2020-02774
000878318 082__ $$a620
000878318 1001_ $$0P:(DE-HGF)0$$aKrause, Simon$$b0
000878318 245__ $$aThe impact of crystal size and temperature on the adsorption-induced flexibility of the Zr-based metal–organic framework DUT-98
000878318 260__ $$aFrankfurt, M.$$bBeilstein-Institut zur Förderung der Chemischen Wissenschaften$$c2019
000878318 3367_ $$2DRIVER$$aarticle
000878318 3367_ $$2DataCite$$aOutput Types/Journal article
000878318 3367_ $$0PUB:(DE-HGF)16$$2PUB:(DE-HGF)$$aJournal Article$$bjournal$$mjournal$$s1596719628_31984
000878318 3367_ $$2BibTeX$$aARTICLE
000878318 3367_ $$2ORCID$$aJOURNAL_ARTICLE
000878318 3367_ $$00$$2EndNote$$aJournal Article
000878318 520__ $$aIn this contribution we analyze the influence of adsorption cycling, crystal size, and temperature on the switching behavior of the flexible Zr-based metal–organic framework DUT-98. We observe a shift in the gate-opening pressure upon cycling of adsorption experiments for micrometer-sized crystals and assign this to a fragmentation of the crystals. In a series of samples, the average crystal size of DUT-98 crystals was varied from 120 µm to 50 nm and the obtained solids were characterized by X-ray diffraction, infrared spectroscopy, as well as scanning and transmission electron microscopy. We analyzed the adsorption behavior by nitrogen and water adsorption at 77 K and 298 K, respectively, and show that adsorption-induced flexibility is only observed for micrometer-sized crystals. Nanometer-sized crystals were found to exhibit reversible type I adsorption behavior upon adsorption of nitrogen and exhibit a crystal-size-dependent steep water uptake of up to 20 mmol g−1 at 0.5 p/p0 with potential for water harvesting and heat pump applications. We furthermore investigate the temperature-induced structural transition by in situ powder X-ray diffraction. At temperatures beyond 110 °C, the open-pore state of the nanometer-sized DUT-98 crystals is found to irreversibly transform to a closed-pore state. The connection of crystal fragmentation upon adsorption cycling and the crystal size dependence of the adsorption-induced flexibility is an important finding for evaluation of these materials in future adsorption-based applications. This work thus extends the limited amount of studies on crystal size effects in flexible MOFs and hopefully motivates further investigations in this field.
000878318 536__ $$0G:(DE-HGF)POF3-143$$a143 - Controlling Configuration-Based Phenomena (POF3-143)$$cPOF3-143$$fPOF III$$x0
000878318 536__ $$0G:(GEPRIS)167917811$$aDFG project 167917811 - SFB 917: Resistiv schaltende Chalkogenide für zukünftige Elektronikanwendungen: Struktur, Kinetik und Bauelementskalierung "Nanoswitches" (167917811)$$c167917811$$x1
000878318 588__ $$aDataset connected to CrossRef
000878318 7001_ $$00000-0002-9851-5031$$aBon, Volodymyr$$b1
000878318 7001_ $$0P:(DE-Juel1)145710$$aDu, Hongchu$$b2
000878318 7001_ $$0P:(DE-Juel1)144121$$aDunin-Borkowski, Rafal E$$b3
000878318 7001_ $$0P:(DE-HGF)0$$aStoeck, Ulrich$$b4
000878318 7001_ $$00000-0001-7052-1029$$aSenkovska, Irena$$b5
000878318 7001_ $$0P:(DE-HGF)0$$aKaskel, Stefan$$b6$$eCorresponding author
000878318 773__ $$0PERI:(DE-600)2583584-1$$a10.3762/bjnano.10.169$$gVol. 10, p. 1737 - 1744$$p1737 - 1744$$tBeilstein journal of nanotechnology$$v10$$x2190-4286$$y2019
000878318 8564_ $$uhttps://juser.fz-juelich.de/record/878318/files/2190-4286-10-169.pdf$$yOpenAccess
000878318 8564_ $$uhttps://juser.fz-juelich.de/record/878318/files/2190-4286-10-169.pdf?subformat=pdfa$$xpdfa$$yOpenAccess
000878318 909CO $$ooai:juser.fz-juelich.de:878318$$pdnbdelivery$$pdriver$$pVDB$$popen_access$$popenaire
000878318 9101_ $$0I:(DE-HGF)0$$60000-0002-9851-5031$$aExternal Institute$$b1$$kExtern
000878318 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)145710$$aForschungszentrum Jülich$$b2$$kFZJ
000878318 9101_ $$0I:(DE-588b)5008462-8$$6P:(DE-Juel1)144121$$aForschungszentrum Jülich$$b3$$kFZJ
000878318 9101_ $$0I:(DE-HGF)0$$60000-0001-7052-1029$$aExternal Institute$$b5$$kExtern
000878318 9131_ $$0G:(DE-HGF)POF3-143$$1G:(DE-HGF)POF3-140$$2G:(DE-HGF)POF3-100$$3G:(DE-HGF)POF3$$4G:(DE-HGF)POF$$aDE-HGF$$bEnergie$$lFuture Information Technology - Fundamentals, Novel Concepts and Energy Efficiency (FIT)$$vControlling Configuration-Based Phenomena$$x0
000878318 9141_ $$y2020
000878318 915__ $$0StatID:(DE-HGF)0200$$2StatID$$aDBCoverage$$bSCOPUS$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0160$$2StatID$$aDBCoverage$$bEssential Science Indicators$$d2020-01-17
000878318 915__ $$0LIC:(DE-HGF)CCBY4$$2HGFVOC$$aCreative Commons Attribution CC BY 4.0
000878318 915__ $$0StatID:(DE-HGF)0100$$2StatID$$aJCR$$bBEILSTEIN J NANOTECH : 2018$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0501$$2StatID$$aDBCoverage$$bDOAJ Seal$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0500$$2StatID$$aDBCoverage$$bDOAJ$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0111$$2StatID$$aWoS$$bScience Citation Index Expanded$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0150$$2StatID$$aDBCoverage$$bWeb of Science Core Collection$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)9900$$2StatID$$aIF < 5$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0510$$2StatID$$aOpenAccess
000878318 915__ $$0StatID:(DE-HGF)0030$$2StatID$$aPeer Review$$bDOAJ : Peer review$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)1150$$2StatID$$aDBCoverage$$bCurrent Contents - Physical, Chemical and Earth Sciences$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0300$$2StatID$$aDBCoverage$$bMedline$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0320$$2StatID$$aDBCoverage$$bPubMed Central$$d2020-01-17
000878318 915__ $$0StatID:(DE-HGF)0199$$2StatID$$aDBCoverage$$bClarivate Analytics Master Journal List$$d2020-01-17
000878318 920__ $$lyes
000878318 9201_ $$0I:(DE-Juel1)ER-C-1-20170209$$kER-C-1$$lPhysik Nanoskaliger Systeme$$x0
000878318 9201_ $$0I:(DE-Juel1)ER-C-2-20170209$$kER-C-2$$lMaterialwissenschaft u. Werkstofftechnik$$x1
000878318 980__ $$ajournal
000878318 980__ $$aVDB
000878318 980__ $$aUNRESTRICTED
000878318 980__ $$aI:(DE-Juel1)ER-C-1-20170209
000878318 980__ $$aI:(DE-Juel1)ER-C-2-20170209
000878318 9801_ $$aFullTexts