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100 1 _ |a Pradeep, K. G.
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245 _ _ |a Nano-scale Si segregation and precipitation in Cr 2 Al(Si)C MAX phase coatings impeding grain growth during oxidation
260 _ _ |a London [u.a.]
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520 _ _ |a We recently reported that the columnar grain width of Cr2AlC MAX phase coatings increases during oxidation (4 h at 1120°C) by 80%, while for 0.7 at.% Si additions to Cr2AlC, coarsening of only 12% was observed. Here, we use nm scale compositional and microstructural investigations to identify significant differences between Cr2AlC and Cr2Al(Si)C. In particular, needle-shaped precipitates coarsen into globular Cr3Si precipitates upon oxidation in the Si-containing MAX phase. We infer that the presence of these precipitates, which are located predominantly along grain boundaries in the MAX phase, retards coarsening during oxidation by Zener pinning.
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700 1 _ |a Chang, K.
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700 1 _ |a Kovacs, Andras
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700 1 _ |a Sen, S.
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700 1 _ |a Marshal, A.
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700 1 _ |a de Kloe, René
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700 1 _ |a Dunin-Borkowski, R. E.
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700 1 _ |a Schneider, J. M.
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773 _ _ |a 10.1080/21663831.2019.1572663
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