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@ARTICLE{Hou:878355,
      author       = {Hou, Tingting and Luo, Nengchao and Cui, Yi-Tao and Lu,
                      Jianmin and Li, Lei and MacArthur, Katherine E. and Heggen,
                      Marc and Chen, Ruotian and Fan, Fengtao and Tian, Wenming
                      and Jin, Shengye and Wang, Feng},
      title        = {{S}elective reduction of {CO}2 to {CO} under visible light
                      by controlling coordination structures of
                      {C}e{O}x-{S}/{Z}n{I}n2{S}4 hybrid catalysts},
      journal      = {Applied catalysis / B Environmental},
      volume       = {245},
      issn         = {0926-3373},
      address      = {Amsterdam},
      publisher    = {Elsevier},
      reportid     = {FZJ-2020-02802},
      pages        = {262 - 270},
      year         = {2019},
      abstract     = {Engineering the electronic properties of heterogeneous
                      catalysts is an important strategy to enhance their activity
                      towards CO2 reduction. Herein, we prepared partially
                      sulfurized cerium oxide (CeOx-S) nanoclusters with the size
                      less than 2 nm on the surface of ZnIn2S4 layers. Surface
                      electronic properties of CeOx-S nanoclusters are facilely
                      modulated by cerium coordination to sulfur, inducing the
                      emergence of abundant Ce3+ and oxygen vacancies. For the
                      photoreduction of CO2, CeOx-S/ZnIn2S4 hybrid catalysts
                      exhibited a CO productivity of 1.8 mmol g−1 with a rate
                      of 0.18 mmol g−1 h−1, which was twice as higher as
                      that of ZnIn2S4 catalyst using triethylamine as a
                      sacrificial electron donor. Further mechanistic studies
                      reveal that the photogenerated electrons are trapped by
                      oxygen vacancies on CeOx-S/ZnIn2S4 catalysts and
                      subsequently transfer to CO2, benefiting the activation of
                      CO2. Moreover, the extremely high selectivity of CO is
                      derived from the weak adsorption of CO on the surface of
                      CeOx-S/ZnIn2S4 catalysts.},
      cin          = {ER-C-1 / PGI-5},
      ddc          = {540},
      cid          = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)PGI-5-20110106},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000467661700025},
      doi          = {10.1016/j.apcatb.2018.12.059},
      url          = {https://juser.fz-juelich.de/record/878355},
}