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@ARTICLE{Collins:878356,
      author       = {Collins, Sean M. and MacArthur, Katherine E. and Longley,
                      Louis and Tovey, Robert and Benning, Martin and Schönlieb,
                      Carola-Bibiane and Bennett, Thomas D. and Midgley, Paul A.},
      title        = {{P}hase diagrams of liquid-phase mixing in multi-component
                      metal-organic framework glasses constructed by quantitative
                      elemental nano-tomography143},
      journal      = {APL materials},
      volume       = {7},
      number       = {9},
      issn         = {2166-532X},
      address      = {Melville, NY},
      publisher    = {AIP Publ.},
      reportid     = {FZJ-2020-02803},
      pages        = {091111 -},
      year         = {2019},
      note         = {Helmholtz Postdoctoral Fellowship},
      abstract     = {Several distinct mixing processes and resulting
                      microstructures have recently been reported in
                      multicomponent glasses prepared from multiple metal-organic
                      frameworks. Here, two illustrative examples of
                      multicomponent zeolitic imidazolate framework (ZIF) glasses,
                      the (aTZIF-4-Co)0.5(agZIF-62)0.5 blend and the
                      ag[(ZIF-67)0.2(ZIF-62)0.8] flux melted glass, are studied.
                      These materials are characterized by quantitative X-ray
                      energy dispersive spectroscopy in the scanning transmission
                      electron microscope. By advancing a partial ionization cross
                      section methodology using standards of arbitrary morphology,
                      quantitative nanoscale elemental analysis throughout the
                      glass volume is achieved. In turn, phase diagrams describing
                      the mixing states are presented, offering mechanistic
                      insight into the formation of the observed microstructures.
                      Significant miscibility was observed in
                      ag[(ZIF-67)0.2(ZIF-62)0.8]. These findings establish
                      phase-segregation and interdiffusion as two processes in
                      multicomponent glass formation, which explains the different
                      outcomes observed in blending and flux meltin},
      cin          = {ER-C-1 / PGI-5},
      ddc          = {600},
      cid          = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)PGI-5-20110106},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000489245900001},
      doi          = {10.1063/1.5120093},
      url          = {https://juser.fz-juelich.de/record/878356},
}