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@ARTICLE{Marino:878395,
      author       = {Marino, Emanuele and Keller, Austin W. and An, Di and van
                      Dongen, Sjoerd and Kodger, Thomas E. and MacArthur,
                      Katherine E. and Heggen, Marc and Kagan, Cherie R. and
                      Murray, Christopher B. and Schall, Peter},
      title        = {{F}avoring the {G}rowth of {H}igh-{Q}uality,
                      {T}hree-{D}imensional {S}upercrystals of {N}anocrystals},
      journal      = {The journal of physical chemistry / C},
      volume       = {124},
      number       = {20},
      issn         = {1932-7455},
      address      = {Washington, DC},
      publisher    = {Soc.},
      reportid     = {FZJ-2020-02831},
      pages        = {11256 - 11264},
      year         = {2020},
      abstract     = {A recently developed emulsion-templated assembly method
                      promises the scalable, low-cost, and reproducible
                      fabrication of hierarchical nanocrystal (NC)
                      superstructures. These superstructures derive properties
                      from the unique combination of choices of NC building blocks
                      and superstructure morphology and therefore realize the
                      concept of “artificial solids”. To control the final
                      properties of these superstructures, it is essential to
                      control the assembly conditions that yield distinct
                      architectural morphologies. Here, we explore the phase-space
                      of experimental parameters describing the emulsion-templated
                      assembly including temperature, interfacial tension, and NC
                      polydispersity and demonstrate which conditions lead to the
                      growth of the most crystalline NC superstructures or
                      supercrystals. By using a combination of electron microscopy
                      and small-angle X-ray scattering, we show that slower
                      assembly kinetics, softer interfaces, and lower NC
                      polydispersity contribute to the formation of supercrystals
                      with grain sizes up to 600 nm, while reversing these trends
                      yields glassy solids. These results provide a clear path to
                      the realization of higher-quality supercrystals, necessary
                      to many applications.},
      cin          = {ER-C-1},
      ddc          = {530},
      cid          = {I:(DE-Juel1)ER-C-1-20170209},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
      pid          = {G:(DE-HGF)POF3-143},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000537428000051},
      doi          = {10.1021/acs.jpcc.0c02805},
      url          = {https://juser.fz-juelich.de/record/878395},
}