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@ARTICLE{Zhang:878449,
author = {Zhang, Xiaotong and Wu, Baohu and Sun, Shengtong and Wu,
Peiyi},
title = {{H}ybrid {M}aterials from
{U}ltrahigh‐{I}norganic‐{C}ontent {M}ineral {P}lastic
{H}ydrogels: {A}rbitrarily {S}hapeable, {S}trong, and
{T}ough},
journal = {Advanced functional materials},
volume = {30},
number = {19},
issn = {1616-3028},
address = {Weinheim},
publisher = {Wiley-VCH},
reportid = {FZJ-2020-02857},
pages = {1910425 -},
year = {2020},
abstract = {Natural mineralized structural materials such as nacre and
bone possess a unique hierarchical structure comprising both
hard and soft phases, which can achieve the perfect balance
between mechanical strength and shape controllability.
Nevertheless, it remains a great challenge to control the
complex and predesigned shapes of artificial
organic–inorganic hybrid materials at ambient conditions.
Inspired by the plasticity of polymer‐induced liquid
precursor phases that can penetrate and solidify in porous
organic frameworks for biomineral formation, here a mineral
plastic hydrogel is shown with ultrahigh silica content
(≈95 $wt\%)$ that can be similarly hybridized into a
porous delignified wood scaffold, and the resultant
composite hydrogels can be manually made into arbitrary
shapes. Subsequent air drying well preserves the designed
shapes and produces fire‐retardant, ultrastrong, and tough
structural organic–inorganic hybrids. The proposed mineral
plastic hydrogel strategy opens an easy and eco‐friendly
way for fabricating bioinspired structural materials that
compromise both precise shape control and high mechanical
strength.},
cin = {JCNS-FRM-II / JCNS-1 / JCNS-2 / MLZ},
ddc = {530},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-Juel1)JCNS-2-20110106 /
I:(DE-588b)4597118-3},
pnm = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000533998000038},
doi = {10.1002/adfm.201910425},
url = {https://juser.fz-juelich.de/record/878449},
}