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@ARTICLE{Jia:878450,
author = {Jia, Wei and Wu, Baohu and Sun, Shengtong and Wu, Peiyi},
title = {{I}nterfacially stable {MOF} nanosheet membrane with
tailored nanochannels for ultrafast and thermo-responsive
nanofiltration},
journal = {Nano research},
volume = {13},
issn = {1998-0000},
address = {New York, NY [u.a.]},
publisher = {Springer},
reportid = {FZJ-2020-02858},
pages = {2973-2978},
year = {2020},
abstract = {Two-dimensional nanosheet membranes with responsive
nanochannels are appealing for controlled mass
transfer/separation, but limited by everchanging thicknesses
arising from unstable interfaces. Herein, an interfacially
stable, thermo-responsive nanosheet membrane is assembled
from twin-chain stabilized metal-organic framework (MOF)
nanosheets, which function via two cyclic amide-bearing
polymers, thermo-responsive poly(N-vinyl caprolactam) (PVCL)
for adjusting channel size, and non-responsive
polyvinylpyrrolidone for supporting constant interlayer
distance. Owing to the microporosity of MOF nanosheets and
controllable interface wettability, the hybrid membrane
demonstrates both superior separation performance and stable
thermo-responsiveness. Scattering and correlation
spectroscopic analyses further corroborate the respective
roles of the two polymers and reveal the microenvironment
changes of nanochannels are motivated by the dehydration of
PVCL chains.},
cin = {JCNS-FRM-II / JCNS-1 / MLZ / JCNS-4},
ddc = {660},
cid = {I:(DE-Juel1)JCNS-FRM-II-20110218 /
I:(DE-Juel1)JCNS-1-20110106 / I:(DE-588b)4597118-3 /
I:(DE-Juel1)JCNS-4-20201012},
pnm = {6215 - Soft Matter, Health and Life Sciences (POF3-621) /
6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623)
/ 6G15 - FRM II / MLZ (POF3-6G15)},
pid = {G:(DE-HGF)POF3-6215 / G:(DE-HGF)POF3-6G4 /
G:(DE-HGF)POF3-6G15},
experiment = {EXP:(DE-MLZ)NOSPEC-20140101},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000555405300002},
doi = {10.1007/s12274-020-2959-6},
url = {https://juser.fz-juelich.de/record/878450},
}