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@ARTICLE{Lan:878640,
      author       = {Lan, Tu and Tsai, Chih-Long and Tietz, Frank and Wei,
                      Xian-Kui and Heggen, Marc and Dunin-Borkowski, Rafal E. and
                      Wang, Rui and Xiao, Yinguo and Ma, Qianli and Guillon,
                      Olivier},
      title        = {{R}oom-temperature all-solid-state sodium batteries with
                      robust ceramic interface between rigid electrolyte and
                      electrode materials},
      journal      = {Nano energy},
      volume       = {65},
      issn         = {2211-2855},
      address      = {Amsterdam [u.a.]},
      publisher    = {Elsevier},
      reportid     = {FZJ-2020-02968},
      pages        = {104040 -},
      year         = {2019},
      abstract     = {All-solid-state sodium batteries (Na-ASSBs) are regarded as
                      an ecologic and economical alternative to their Li congeners
                      for stationary applications. Ceramic-based Na-ASSBs benefit
                      from the high conductivity of the oxide Na-ion conductors
                      used as electrolyte, as well as from their good mechanical,
                      chemical and thermodynamic stability. However, so far
                      Na-ASSBs suffer from severe contact problems in the positive
                      electrodes and subsequently unsatisfactory cell performance.
                      In this report, the inter-ceramic contact problems are
                      solved by combining the infiltration of a porous electrolyte
                      scaffold by precursor solution with in situ synthesis of
                      electrode active material (chemical infiltration) to
                      fabricate model cells using Na3V2P3O12 (NVP),
                      Na3.4Zr2Si2.4P0.6O12 (NZSP) and Na as the positive
                      electrode, electrolyte and negative electrode materials,
                      respectively. Optimized interface between NVP nano layer and
                      NZSP backbone was formed, providing effective ion transfer
                      and minimizing the stress caused by volume change of
                      electrode active material during charging and discharging
                      processes. The interface resulted in a highly stable battery
                      performance at 25 °C. The performances, achieved without
                      using any liquid or polymer phase as an accommodation
                      medium, suggest a promising future for chemical infiltration
                      as fabrication process for ceramic-based ASSBs.},
      cin          = {ER-C-1 / IEK-1 / JARA-ENERGY},
      ddc          = {660},
      cid          = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)IEK-1-20101013 /
                      $I:(DE-82)080011_20140620$},
      pnm          = {143 - Controlling Configuration-Based Phenomena (POF3-143)
                      / 131 - Electrochemical Storage (POF3-131)},
      pid          = {G:(DE-HGF)POF3-143 / G:(DE-HGF)POF3-131},
      typ          = {PUB:(DE-HGF)16},
      UT           = {WOS:000496445600067},
      doi          = {10.1016/j.nanoen.2019.104040},
      url          = {https://juser.fz-juelich.de/record/878640},
}