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@ARTICLE{Leffler:878651,
author = {Leffler, Vanessa B. and Mayr, Lina and Paciok, Paul and Du,
Hongchu and Dunin‐Borkowski, Rafal E. and Dulle, Martin
and Förster, Stephan},
title = {{C}ontrolled {A}ssembly of {B}lock {C}opolymer {C}oated
{N}anoparticles in 2{D} {A}rrays},
journal = {Angewandte Chemie},
volume = {131},
number = {25},
issn = {1521-3757},
address = {Weinheim},
publisher = {Wiley-VCH65543},
reportid = {FZJ-2020-02972},
pages = {8629-8633},
year = {2019},
abstract = {The defined assembly of nanoparticles (NPs) in polymer
matrices is an important prerequisite for next‐generation
functional materials. A promising approach to control NP
positions in polymer matrices at the nanometer scale is the
use of block copolymers. It allows the selective deposition
of NPs in nanodomains, but the final defined and ordered
positioning of the NPs within the domains has not been
possible. This can now be achieved by coating NPs with block
copolymers. The self‐assembly of block copolymer‐coated
NPs directly leads to ordered microdomains containing
ordered NP arrays with exactly one NP per unit cell. By
variation of the grafting density, the inter‐nanoparticle
distance can be controlled from direct NP surface contact to
surface separations of several nanometers, determined by the
thickness of the polymer shell. The method can be applied to
a wide variety of block copolymers and NPs and is thus
suitable for a broad range of applications.},
cin = {ER-C-1 / ER-C-2},
ddc = {660},
cid = {I:(DE-Juel1)ER-C-1-20170209 / I:(DE-Juel1)ER-C-2-20170209},
pnm = {143 - Controlling Configuration-Based Phenomena (POF3-143)},
pid = {G:(DE-HGF)POF3-143},
typ = {PUB:(DE-HGF)16},
doi = {10.1002/ange.201901913},
url = {https://juser.fz-juelich.de/record/878651},
}