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000878669 1001_ $$0P:(DE-HGF)0$$aSimon, Paul$$b0
000878669 245__ $$aStructural complexity of the intermetallic compound o-Al13Co4
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000878669 520__ $$aThe crystal structure of the complex intermetallic phase o-Al13Co4 was first investigated in 1994, but some open questions still remained. The new refinement of the crystal structure using high-resolution X-ray diffraction data resulted in a much more complex model including a large number of split positions (space group Pnm21, a = 8.1590(6) Å, b = 12.349(1) Å, c = 14.453(1) Å). The model is interpreted in terms of local violation of the translational symmetry, which is confirmed by HRTEM and HRSTEM investigations. Chemical bonding between two partial structures in o-Al13Co4 - three-dimensional framework and linear Co–Al–Co groups in cages of the latter – along with the stacking faults (local twinning) are discussed as possible reasons for such an extended disorder. Previous article in issue
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000878669 7001_ $$0P:(DE-HGF)0$$aZelenina, Iryna$$b1
000878669 7001_ $$0P:(DE-HGF)0$$aRamlau, Reiner$$b2
000878669 7001_ $$0P:(DE-HGF)0$$aCarrillo-Cabrera, Wilder$$b3
000878669 7001_ $$0P:(DE-HGF)0$$aBurkhardt, Ulrich$$b4
000878669 7001_ $$0P:(DE-HGF)0$$aBorrmann, Horst$$b5
000878669 7001_ $$0P:(DE-HGF)0$$aGil, Raul Cardoso$$b6
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000878669 7001_ $$0P:(DE-HGF)0$$aGille, Peter$$b8
000878669 7001_ $$0P:(DE-HGF)0$$aGrin, Yuri$$b9$$eCorresponding author
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000878669 8564_ $$uhttps://juser.fz-juelich.de/record/878669/files/AL13Co4_manuscript_submitted.pdf$$yPublished on 2019-12-10. Available in OpenAccess from 2021-12-10.
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