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@ARTICLE{Simon:878669,
author = {Simon, Paul and Zelenina, Iryna and Ramlau, Reiner and
Carrillo-Cabrera, Wilder and Burkhardt, Ulrich and Borrmann,
Horst and Gil, Raul Cardoso and Feuerbacher, Michael and
Gille, Peter and Grin, Yuri},
title = {{S}tructural complexity of the intermetallic compound
o-{A}l13{C}o4},
journal = {Journal of alloys and compounds},
volume = {820},
issn = {0925-8388},
address = {Amsterdam [u.a.]},
publisher = {ScienceDirect},
reportid = {FZJ-2020-02990},
pages = {153363 -},
year = {2020},
abstract = {The crystal structure of the complex intermetallic phase
o-Al13Co4 was first investigated in 1994, but some open
questions still remained. The new refinement of the crystal
structure using high-resolution X-ray diffraction data
resulted in a much more complex model including a large
number of split positions (space group Pnm21, a = 8.1590(6)
Å, b = 12.349(1) Å, c = 14.453(1) Å). The model is
interpreted in terms of local violation of the translational
symmetry, which is confirmed by HRTEM and HRSTEM
investigations. Chemical bonding between two partial
structures in o-Al13Co4 - three-dimensional framework and
linear Co–Al–Co groups in cages of the latter – along
with the stacking faults (local twinning) are discussed as
possible reasons for such an extended disorder. Previous
article in issue},
cin = {PGI-5},
ddc = {540},
cid = {I:(DE-Juel1)PGI-5-20110106},
pnm = {144 - Controlling Collective States (POF3-144)},
pid = {G:(DE-HGF)POF3-144},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000507854700139},
doi = {10.1016/j.jallcom.2019.153363},
url = {https://juser.fz-juelich.de/record/878669},
}