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100 1 _ |a Simon, Paul
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245 _ _ |a Structural complexity of the intermetallic compound o-Al13Co4
260 _ _ |a Amsterdam [u.a.]
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520 _ _ |a The crystal structure of the complex intermetallic phase o-Al13Co4 was first investigated in 1994, but some open questions still remained. The new refinement of the crystal structure using high-resolution X-ray diffraction data resulted in a much more complex model including a large number of split positions (space group Pnm21, a = 8.1590(6) Å, b = 12.349(1) Å, c = 14.453(1) Å). The model is interpreted in terms of local violation of the translational symmetry, which is confirmed by HRTEM and HRSTEM investigations. Chemical bonding between two partial structures in o-Al13Co4 - three-dimensional framework and linear Co–Al–Co groups in cages of the latter – along with the stacking faults (local twinning) are discussed as possible reasons for such an extended disorder. Previous article in issue
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700 1 _ |a Zelenina, Iryna
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700 1 _ |a Ramlau, Reiner
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700 1 _ |a Carrillo-Cabrera, Wilder
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700 1 _ |a Burkhardt, Ulrich
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700 1 _ |a Gil, Raul Cardoso
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700 1 _ |a Gille, Peter
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700 1 _ |a Grin, Yuri
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773 _ _ |a 10.1016/j.jallcom.2019.153363
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856 4 _ |y Published on 2019-12-10. Available in OpenAccess from 2021-12-10.
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856 4 _ |y Published on 2019-12-10. Available in OpenAccess from 2021-12-10.
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