| Home > Publications database > Structural complexity of the intermetallic compound o-Al13Co4 > print |
| 001 | 878669 | ||
| 005 | 20240610121256.0 | ||
| 024 | 7 | _ | |a 10.1016/j.jallcom.2019.153363 |2 doi |
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| 245 | _ | _ | |a Structural complexity of the intermetallic compound o-Al13Co4 |
| 260 | _ | _ | |a Amsterdam [u.a.] |c 2020 |b ScienceDirect |
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| 520 | _ | _ | |a The crystal structure of the complex intermetallic phase o-Al13Co4 was first investigated in 1994, but some open questions still remained. The new refinement of the crystal structure using high-resolution X-ray diffraction data resulted in a much more complex model including a large number of split positions (space group Pnm21, a = 8.1590(6) Å, b = 12.349(1) Å, c = 14.453(1) Å). The model is interpreted in terms of local violation of the translational symmetry, which is confirmed by HRTEM and HRSTEM investigations. Chemical bonding between two partial structures in o-Al13Co4 - three-dimensional framework and linear Co–Al–Co groups in cages of the latter – along with the stacking faults (local twinning) are discussed as possible reasons for such an extended disorder. Previous article in issue |
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| 700 | 1 | _ | |a Grin, Yuri |0 P:(DE-HGF)0 |b 9 |e Corresponding author |
| 773 | _ | _ | |a 10.1016/j.jallcom.2019.153363 |g Vol. 820, p. 153363 - |0 PERI:(DE-600)2012675-X |p 153363 - |t Journal of alloys and compounds |v 820 |y 2020 |x 0925-8388 |
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| 856 | 4 | _ | |y Published on 2019-12-10. Available in OpenAccess from 2021-12-10. |u https://juser.fz-juelich.de/record/878669/files/AL13Co4_manuscript_submitted.pdf |
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